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C(6)H(5)NH(2) overset(NaNO(2)+HCl)unders...

`C_(6)H_(5)NH_(2) overset(NaNO_(2)+HCl)underset(0-5^(@)C) X overset(H_(2)O)underset(Delta)toY,` the product is :

A

Benzenediazonium chloride

B

Nitrobenzene

C

Phenol

D

Cresol

Text Solution

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The correct Answer is:
C
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In the series of reaction C_(6)H_(5)NH_(2)overset(NaNO_(2)//HCl)underset(0-5^(@)C)rarr X overset(HNO_(2))underset(H_(2)O)rarr Y+N_(2)+HCl , X and Y are respectively

C_(6) H_(5)NH_(2) underset (0-5^(@))overset(HNO_(2)//HCI)to X underset(H_(2)O)overset(Delta)to Phenol, Here X is :

Identify X, Y and Z in the following reactions: (a) C_(6)H_(6)underset(AlCl_(3))overset(Cl_(2))toXunderset(575K,300atm)overset(aq.NaOH)toYoverset(H^(+),H_(2)O)toZ (b) C_(6)H_(5)NH_(2)underset(273K)overset(NaNO_(2).HCl)toXunderset("Warm")overset(H^(+),H_(2)O)toYunderset("Heat")overset(Zn)toZ

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Give the structures of A, B and C in the following reactions (i) CH_(3)CH_(2)I overset(NaCN)(to) A underset("hydrolysis Partial")overset(OH^(-))(to) B overset(NaOH+Br_(2))to C (ii) C_(6)H_(5)N_(2)Cl overset(CuCN)to A overset(H_(2)O // H^(+))(to) B underset(Delta)overset(NH_(3))(to) C (iii) CH_(3)CH_(2)Br overset(KCN)to A overset(LiAlH_(4))to B underset(0^(@)C)overset(HNO_(2))to C (iv) C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(NaNO_(2)+HCl)to B underset(Delta)overset(H_(2)O // H^(+))to C (v) CH_(3)COOH underset(Delta)overset(NH_(3))to A overset(NaOBr)to B overset(NaNO_(2)//HCl)to C (vi) C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(HNO_(2))to B overset(C_(6)H_(5)OH)to C

RESONANCE-AROMATIC COMPOUNDS-Part - II Only one option correct type
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  8. The best reagent for converting, 2-phenylpropanamide into 1-phenyletha...

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  9. In order to prepare a 1^(@) amine from an alkyl halide with simultaneo...

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  10. Best method for preparing primary amines from alkyl halides without ch...

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  11. The product formed by the reaction of acetamide with bromine in presen...

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  12. In the reaction, C(6)H(5)NH(2)underset(0-5^(@)C)overset(NaNO(2)+HCl)...

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  13. Benzenediazonium chloride can be converted into benzene on treatment w...

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  14. C(6)H(5)NH(2) overset(NaNO(2)+HCl)underset(0-5^(@)C) X overset(H(2)O)u...

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  15. . The major product (A) is

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  16. Diazonium salt , the reaction is known as

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  17. . The product (B) is

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  18. Which of the following compounds will not undergo azo coupling reactio...

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  19. X (major product ) X will be -

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  20. X will be :

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