Home
Class 12
CHEMISTRY
Hofmann rearrangement In the Hofmann r...

Hofmann rearrangement
In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that has one carbon lesser than starting amide.

In the migrating group is chiral then is configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
Arrange the following amides according to their relative when reacted with `Br_(2)` in excess of strong base :

A

`IV gt I gt II gt III`

B

`II gt I gt III gt IV`

C

`II gt IV gt III gt I`

D

`II gt I gt IV gt III`

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS

    RESONANCE|Exercise Exercise-3 (Part-I) JEE Advanced|36 Videos
  • AROMATIC COMPOUNDS

    RESONANCE|Exercise Part - II JEE MAIN|20 Videos
  • AROMATIC COMPOUNDS

    RESONANCE|Exercise Part-III : One or more than one option correct type|10 Videos
  • ALKYL HALIDE, ALCOHOL, PHENOL, ETHER

    RESONANCE|Exercise ORGANIC CHEMISTRY(Alkyl Halide, Alcohol,Phenol,Ether)|56 Videos
  • BASIC CONCEPTS

    RESONANCE|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos

Similar Questions

Explore conceptually related problems

An unsubstituted amide is converted into the acid nitrogen by: