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Explain the important aspects of resonan...

Explain the important aspects of resonance with reference to the `CO_(3)^(2-)` ion.

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When a molecule cannot be represented by a single structure but its characteristic proporties can be described by two or more than two structures, then the actual structure is said to be a resonance hybrid of these structures. For example, the carbonate ion may be represented as :

In this case, each atom has an octet of electrons. According to this structure, there are single bonds between two carbon - oxygen atoms and one double bond between carbon and oxygen atoms. Therefore the two `C-O` bonds should be different than the third `C=O` bond. However, experimentally, it is observed that all the three bond lengths are equal and teh bonds are intermediate between single and double bonds. This means that the above Lewis structure does not account for the observed experimental facts. To solve the problem, the `CO_(3)^(2-)` may be represented as resonance hybrid of the following structures.
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MODERN PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-NCERT FILE (NCERT)(Textbook Exercises)
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  2. Define the bond length.

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  3. Explain the important aspects of resonance with reference to the CO(3)...

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  4. H(3)PO(3) can be represented by structures I and II shown below. Can t...

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  5. Write the resonance structures for SO(3),NO(2), and NO(3)^(ө).

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  6. Use Lewis symbols to show electron transfer between the following atom...

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  7. Although both CO(2) and H(2)O are triatomic molecules, the shape of H(...

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  8. APPLICATION OF DIPOLE MOMENT

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  9. Define electronegativity. How does it differ from electron gain enthal...

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  10. Explain with the help of suitable example polar covalent bond.

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  12. The skeletal structure of CH(3)COOH as shown below is correct, but som...

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  13. Apart from tetrahedral geometry, another possible geometry for CH(4) i...

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  14. Explain why BeH(2) molecule has a zero dipole moment although the Be-H...

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  15. Which out of NH(3) and NF(3) has higher dipole moment and why?

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  16. What is meant by hybridisation of atomic orbitals? Describe the shape ...

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  17. Describe the change in hybridisation (if any) of the AI atom in the fo...

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  18. Is there any change in hybridisation of the B and N atom as a result o...

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  19. Draw diagrams showing the formation of a double bond and a triple bond...

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  20. What is the total number of sigma and pi bonds in the following molecu...

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