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The geometry of I(3)^(-) is...

The geometry of `I_(3)^(-)` is

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The central I atom has the ground state electronic configuration as `5s^(2)5p^(5)`. It involves `sp^(3)d` hybridization involving one `5s`, three 5p and one vacant 5d orbital. The half filled `sp^(3)d` hybrid orbital forms a covalent bond with one I atom and an empty `sp^(3)d` hybrid orbital accepts an electron pair from `I^(-)` ion to form a coordinate bond. Thus, the geometry of the molecule is trigonal bipyramidal in which three positions are occupied by lone pairs.

Because of the equivalent positions of lone pairs the resulting `I_(3)^(-)` ion is linear.
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Hybridization is a concept of mixing or merging of orbitals of same atom with slight differences in energies to redistribute their energies and give new orbitals of equivalent energy called 'Hybrid Orbitals'. Hybridisation is a hypothetical concept and never actually exists. One should not be confused by a common misconception that hybridization is responsible for particular geometry. Geometry of a molecule is decided by energy factor not by hybridization. It is the orbital (which may be half filled, completely filled or empty) that undergoes hybridization and not the electron. The bond angles in hybridised orbitals are influenced by presence of lone pair, presence of multiple bonds, presence of one electron and electronegativity of atom. An increase in s-character of hybridised orbitals results in decrease in size of orbitals. This results in decrease in bond length and increase in energy. Among the following which have the same molecular geometry? (P) I_(3)^(-) (Q) XeF_(4) (R) BrF_(4)^(-) (S) XeO_(2)F_(2)

MODERN PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-HIGHER ORDER THINKING SKILLS
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