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Which of the following pairs have identi...

Which of the following pairs have identical bond order?

A

`CN^(-) and NO^(+)`

B

`CN^(-) and O_(2)^(-)`

C

`CN^(-) and CN^(+)`

D

`NO^(+) and O_(2)^(-)`

Text Solution

Verified by Experts

The correct Answer is:
A

`CN^(-):KK(sigma2s)^(2)(sigma^(**)2s)^(2)(pi2p_(x))^(2)=(pi2p_(y))^(2)(sigma2p_(z))^(2)`
`"B.O."=(8-2)/(2)=3`
`NO^(+):KK(sigma2s)^(2)(sigma^(**)2s)^(2)(pi2p_(x))^(2)=(pi2p_(y))^(2)(sigma2p_(z))^(2)`
`"B.O."=(8-2)/(2)=3`
`O_(2)^(-):KK(sigma2s)^(2)(sigma^(**)2s)^(2)(sigma2p_(z))^(2)(pi2p_(x))^(2)(pi2p_(y))^(2)(pi^(**)2p_(x))^(2)(pi^(**)2p_(y))^(1)`
`"B.O."=(8-5)/(2)=1.5`
`CN^(-) and NO^(+)` have same bond order.
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