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The equilibrium constant, K(p) for the r...

The equilibrium constant, `K_(p)` for the reaction
`2SO_(2)(g)+O_(2)(g)hArr 2SO_(3)(g)`
is `4.0 atm^(-1)` at 1000 K. What would be the partial pressure of `SO_(2)` if at equilibrium the amount of `SO_(2)` and `SO_(3)` is the same ?

A

16.0 atm

B

0.25 atm

C

1 atm

D

0.75 atm

Text Solution

Verified by Experts

The correct Answer is:
B

Equal amounts of `SO_(2)` and `SO_(3)` would mean that they would have the same partial pressures.
`K_(p)=(p(SO_(3))^(2))/(p(SO_(2))^(2)xx p(O_(2)))`
Since `p(SO_(3))=p(SO)_(2)`
`therefore K_(p)=(1)/(p(O_(2)))`
or `p(O_(2))=(1)/(K_(p))=(1)/(4)=0.25` atm
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