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The pH of solution obtained by mixing eq...

The pH of solution obtained by mixing equal volumes of two aqueous solutions of pH 5 and pH 3 of the same substance is :

A

`3.5`

B

`4.5`

C

`3.3`

D

4

Text Solution

Verified by Experts

The correct Answer is:
C

Let 100 ml of both the solutions are mixed
`[H^(+)]` in solution of pH = 5 is `10^(-5)`
`[H^(+)]` in solution of pH = 3 is `10^(-3)`
Total `[H^(+)]=10^(-5)+10^(-3)`
`=1.01xx10^(-3)`
Total volume = 2000 ml
Conc. in mixture
`=(1.01xx10^(-3)xx1000)/(2000)=5.05xx10^(-4)`
`pH=-log(5.05xx10^(-4))=3.3`
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