Home
Class 12
CHEMISTRY
Consider the reaction where K(p)=0.497 ...

Consider the reaction where `K_(p)=0.497` at 500 K.
`PCl_(5)(g)hArr PCl_(3)(g)+Cl_(2)(g)`
If the three gases are mixed in a rigid container so that the partial pressure of each gas is initially 1 atm, which is true ?

A

More `PCl_(5)` will be produced

B

More `PCl_(3)` will be produced

C

Equilibrium will be established when 50% reaction is complete

D

None of the above

Text Solution

Verified by Experts

The correct Answer is:
A

`PCl_(5)hArr PCl_(3)+Cl_(2)`
`K_(p)=0.497`
`Q=(P_(PCl_(3))xx P_(Cl_(2)))/(P_(PCl_(5)))=(1xx1)/(1)=1`
Since `Q gt K_(p)`, the reaction will proceed in backward direction. Hence, more `PCl_(5)` will be produced.
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise Multiple Choice Questions (Level - III)|13 Videos
  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise Recent Examination Questions|17 Videos
  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise Recent Examination Questions|17 Videos
  • ENVIROMENTAL POLLUTION

    MODERN PUBLICATION|Exercise RECENT EXAMINATION QUESTIOS|2 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    MODERN PUBLICATION|Exercise Recent Examination Questions|13 Videos
MODERN PUBLICATION-EQUILIBRIUM-Multiple Choice Questions (Level - II)
  1. The hydrogen ion concentration of a 10^(-8) M HCl aqueous solution at ...

    Text Solution

    |

  2. The following equilibrium constants are given : N(2)+3H(2)hArr 2NH...

    Text Solution

    |

  3. Consider the reaction where K(p)=0.497 at 500 K. PCl(5)(g)hArr PC...

    Text Solution

    |

  4. K(p) and K'(p) are equilibrium constants of the two reactions given b...

    Text Solution

    |

  5. The solubility product of a sparingly soluble metal hydroxide, M(OH)(2...

    Text Solution

    |

  6. Determine pH of the solution that results from addition of 20 ml of 0....

    Text Solution

    |

  7. The solubility product of iron (III) hydroxide is 1.6xx10^(-39). If x ...

    Text Solution

    |

  8. When equal volume of the following solutions are mixed, precipitation ...

    Text Solution

    |

  9. Solubility of CaF(2) in terms of its solubility product is given by :

    Text Solution

    |

  10. When 200 ml of aqueous solution of HCl (pH = 2) is mixed with 300 ml o...

    Text Solution

    |

  11. The dissociation constants of acetic acid and HCN at 25^(@)C are 1.5xx...

    Text Solution

    |

  12. The ionisation constant of ammonium hydroxide is 1.77xx10^(-5) at 298 ...

    Text Solution

    |

  13. For the reaction H(2)(g)+I(2)(g)hArr2HI(g), the standard free energy i...

    Text Solution

    |

  14. PCl(5), PCl(3) and Cl(2) are at equilibrium at 500 K in a closed conta...

    Text Solution

    |

  15. When hydrochloric acid is added to cobalt nitrate solution at room tem...

    Text Solution

    |

  16. The pH of neutral water at 25 ^0 C is 7.0. As the temperature increa...

    Text Solution

    |

  17. K(a(1)), K(a(2)) and K(a(3)) are the respective ionisation constants f...

    Text Solution

    |

  18. Acidity of BF(3) can be explained on the basis of which of the followi...

    Text Solution

    |

  19. At 500 K, equilibrium constant, K(c ), for the following reaction is 5...

    Text Solution

    |

  20. Which of the following options will be correct for the stage of half c...

    Text Solution

    |