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The two complexes PtCl(4).2NH(3) and PtC...

The two complexes `PtCl_(4).2NH_(3) and PtCl_(4). 2KCl` do not give precipitates of AgCl when treated with `AgNO_(3)`. The conductance studies indicate zero and three ions per mole of the complex respectively in their solutions. The structures of these complexes are :

A

`[Pt(NH_(3))_(2)Cl_(4)]," " K_(2)[PtCl_(6)]`

B

`[Pt(NH_(3))_(2)]Cl_(4)," " K_(2)[PtCl_(6)]`

C

`[Pt(NH_(3))_(2)Cl_(2)]Cl_(2), " " [K_(2)PtCl_(4)]Cl_(2)`

D

`[Pt(NH_(3))_(2)Cl_(4)], " "[K_(2)PtCl_(6)]`.

Text Solution

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The correct Answer is:
A
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