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Which of the following statement is not ...

Which of the following statement is not correct for `[Ni(CN)_(4)]^(2-) and [NiCl_(4)]^(2-)` complexes.

A

Both have Ni in + II oxidation state.

B

`[NiCl_(4)]^(2-)` is a low spin while `[Ni(CN)_(4)]^(2-)` is a high spin complex.

C

`[NiCl_(4)]^(2-)` is tetrahedral while `[Ni(CN)_(4)]^(2-)` is square planar.

D

`[NiCl_(4)]^(2-)` involves `sp^(3)` hybridisation and `[NiCN_(4)]^(2-)` involves `dsp^(2)` hybridisation.

Text Solution

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The correct Answer is:
B
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MODERN PUBLICATION-COORDINATION COMPOUNDS-Multiple Choice Questions Level-II (Comprehensive Qs)
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  2. The following represents a pair of enantiomers:

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  3. Which of the following statement is not correct for [Ni(CN)(4)]^(2-) a...

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  7. Which of the following will give maximum number of isomers ?

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  12. The compounds [Co(SO(4))(NH(3))(5)]Br and [Co(SO(4))(NH(3))(5)]Cl repr...

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  13. The oxidation number of cobalt in K[Co(CO)4] is : (i) + 1 (ii) + 3 (ii...

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  14. When one mole of each of the following complex salts is treated with e...

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  15. Which of the following will give a pair of enantiomorphs? (en = NH(2...

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  16. What is crystal field splitting energy (CFSE)?

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  17. The hybridization states of [Ni(CO)(4)], [Ni(CN)(4)]^(2-) and [NiCl(4)...

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  18. Which of the following is an outer orbital complex ?

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