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In 1924, de-Broglie proposed that every ...

In 1924, de-Broglie proposed that every particle possesses wave properties with a wavelength , `lambda` given by `lambda = h/(mv)` where m is the mass of the particle, `v` is its velocity and h is Planck's constant. The de-Broglie prediction was confirmed experimentally when it was found that an electron beam undergoes diffraction , a phenomenon characteristic of waves. The de-Broglie wavelength can be estimated by measuring kinetic energy of an electron accelerating by a potential V as :
`1/2 mv^2 = eV "where" 1eV = 1.6 xx 10^(-19) J, h = 6.6 xx 10^(-34) Js`.
If `lambda` is the wavelength associated with the electron in the 4th circular orbit of hydrogen atom, then radius of the orbit is

A

`lambda/(2pi)`

B

`2(lambda)/(pi)`

C

`2/(pi lambda)`

D

`(2 pi)/(lambda)`

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The correct Answer is:
To find the radius of the 4th circular orbit of a hydrogen atom using the de-Broglie wavelength, we can follow these steps: ### Step 1: Understand the relationship between kinetic energy and potential difference The kinetic energy (KE) of an electron accelerating through a potential difference \( V \) is given by: \[ \frac{1}{2} mv^2 = eV \] where \( e \) is the charge of the electron (1 eV = \( 1.6 \times 10^{-19} \) J). ### Step 2: Express velocity in terms of potential difference From the kinetic energy equation, we can solve for \( v \): \[ v = \sqrt{\frac{2eV}{m}} \] ### Step 3: Use de-Broglie's wavelength formula The de-Broglie wavelength \( \lambda \) is given by: \[ \lambda = \frac{h}{mv} \] Substituting the expression for \( v \) from Step 2: \[ \lambda = \frac{h}{m \sqrt{\frac{2eV}{m}}} = \frac{h \sqrt{m}}{\sqrt{2eV}} \] ### Step 4: Relate the radius of the orbit to angular momentum For a circular orbit, the angular momentum \( L \) is quantized and given by: \[ L = mvr = n\frac{h}{2\pi} \] For the 4th orbit, \( n = 4 \): \[ mvr = 4\frac{h}{2\pi} = \frac{2h}{\pi} \] ### Step 5: Solve for the radius \( r \) Now we can express \( r \) in terms of \( \lambda \): \[ r = \frac{2h}{\pi mv} \] Substituting \( mv \) from the de-Broglie wavelength: \[ mv = \frac{h}{\lambda} \] Thus, \[ r = \frac{2h}{\pi \left(\frac{h}{\lambda}\right)} = \frac{2\lambda}{\pi} \] ### Conclusion The radius of the 4th circular orbit of the hydrogen atom is: \[ r = \frac{2\lambda}{\pi} \]

To find the radius of the 4th circular orbit of a hydrogen atom using the de-Broglie wavelength, we can follow these steps: ### Step 1: Understand the relationship between kinetic energy and potential difference The kinetic energy (KE) of an electron accelerating through a potential difference \( V \) is given by: \[ \frac{1}{2} mv^2 = eV \] where \( e \) is the charge of the electron (1 eV = \( 1.6 \times 10^{-19} \) J). ...
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  2. In 1924, de-Broglie proposed that every particle possesses wave proper...

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  3. In 1924, de-Broglie proposed that every particle possesses wave proper...

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  6. The position and energy of an electron is specified with the help of f...

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  7. The position and energy of an electron is specified with the help of f...

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  8. The position and energy of an electron is specified with the help of f...

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  9. The hydrogen -like species Li^(2+) is in a spherically symmetric stat...

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  10. The hydrogen -like species Li^(2+) is in a spherically symmetric stat...

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  11. The hydrogen -like species Li^(2+) is in a spherically symmetric stat...

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  12. The wave function, Psi(n,l,ml) is a mathematical function whose value ...

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  13. The wave function, Psi(n,l,ml) is a mathematical function whose value ...

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  14. The wave function, Psi(n,l,ml) is a mathematical function whose value ...

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  15. Consider the Bohr's model of a one-electron atom where the electron mo...

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  16. Consider the Bohr's model of a one-electron atom where the electron mo...

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