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For an ideal gas C(p) and C(v) are relat...

For an ideal gas `C_(p)` and `C_(v)` are related as

A

`C_(p) - C_(v) = R`

B

`(C_(p))/(C_(v)) = R`

C

`C_(p) + C_(v) = R`

D

`C_(v) - C_(p) = R`

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The correct Answer is:
To find the relationship between the heat capacities \( C_p \) (heat capacity at constant pressure) and \( C_v \) (heat capacity at constant volume) for an ideal gas, we can follow these steps: ### Step-by-Step Solution 1. **Understanding the Definitions**: - \( C_p \) is the heat capacity at constant pressure, defined as: \[ Q = nC_p \Delta T \] - \( C_v \) is the heat capacity at constant volume, defined as: \[ Q = nC_v \Delta T \] 2. **Relating Heat Capacities to Internal Energy and Enthalpy**: - At constant volume, the heat added is equal to the change in internal energy (\( \Delta U \)): \[ Q_v = nC_v \Delta T = \Delta U \] - At constant pressure, the heat added is equal to the change in enthalpy (\( \Delta H \)): \[ Q_p = nC_p \Delta T = \Delta H \] 3. **Using the First Law of Thermodynamics**: - The relationship between enthalpy and internal energy can be expressed as: \[ \Delta H = \Delta U + \Delta (PV) \] - For an ideal gas, using the ideal gas equation \( PV = nRT \): \[ \Delta (PV) = R \Delta T \] 4. **Substituting into the Enthalpy Equation**: - Substitute \( \Delta (PV) \) into the enthalpy equation: \[ \Delta H = \Delta U + R \Delta T \] - Replacing \( \Delta U \) with \( nC_v \Delta T \) gives: \[ nC_p \Delta T = nC_v \Delta T + R \Delta T \] 5. **Simplifying the Equation**: - Dividing through by \( n \Delta T \) (assuming \( \Delta T \neq 0 \)): \[ C_p = C_v + R \] 6. **Final Relation**: - Rearranging gives the final relationship: \[ C_p - C_v = R \] ### Conclusion The relationship between the heat capacities for an ideal gas is: \[ C_p - C_v = R \]
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