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For which of the following reactions, De...

For which of the following reactions, `DeltaS` is not positive :

A

`I_(2)(s) to I_(2)(g)`

B

`CuO(s) + H_(2)(g) to Cu(s) + H_(2)O(l)`

C

`2O_(3) (g) to 3O_(2)(g)`

D

`CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O_(g)`

Text Solution

Verified by Experts

The correct Answer is:
B

`DeltaG^(@) = -Rt "log K`
`(DeltaG^(@))/(RT) = -2.303` log K
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MODERN PUBLICATION-THERMODYNAMICS-Competition File MCQ
  1. The enthaplpy changes state for the following processes are listed bel...

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  2. The entropy change can be calculated by using expression DeltaS = (q(r...

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  3. For which of the following reactions, DeltaS is not positive :

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  4. If equilibrium constant for a reaction is K, then standard free energy...

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  5. For a reversible process at equilibrium, the change in entropy may be ...

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  6. Free energy change is related to enthalpy and entropy changes as:

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  7. For a spontaneous reaction, DeltaG should be :

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  8. Which of the following conditions is not favourable for the feasibilit...

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  9. The standard free energy change DeltaG^(@) is related to equilibrium c...

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  10. If Delta(f)G^(@) for NH(3)(g) is -16.4 kJ "mol"^(-1), thenDeltaG^(@) ...

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  11. For an ideal gas expanding adiabatically in vacuum,

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  12. Which of the following is true for a reaction H(2)O(l)toH(2)O(g) at 10...

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  13. Considering entropy (S) as a thermodynamic parameter, the criterion fo...

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  14. A reaction occurs spontaneously if

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  15. The enthalpy and entropy change for the reaction: Br(2)(l) + CI(2)(g...

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  16. For a spontaneous reaction, the DeltaG, equilibrium constant (K) and E...

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  17. Given that the bond energies of H - H and CI - CI are 430 kJ "mol"^(-...

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  18. If 50 kJ of energy is needed for muscular work to walk a distance of 1...

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  19. The average molar heat capacities of ice and water are respectively 37...

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  20. Entropy changes for the process H(2)O(l) to H(2)O(g) at normal press...

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