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Among the following, the set of paramete...

Among the following, the set of parameters that represents path function is :
(A) q + w (B) q
(C) w (D) H -TS

A

(A) and (D)

B

(B), (C) and (D)

C

(B) and (C)

D

(A), (B) and (C)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding which parameters represent path functions, we need to understand the concepts of state functions and path functions in thermodynamics. ### Step-by-Step Solution: 1. **Define State Functions and Path Functions**: - State functions depend only on the initial and final states of a system, regardless of the path taken to get there. Examples include internal energy (U), enthalpy (H), and Gibbs free energy (G). - Path functions depend on the specific path taken during a process. Examples include heat (q) and work (w). 2. **Analyze the Given Options**: - **(A) q + w**: This represents a change in internal energy (ΔU) according to the first law of thermodynamics (ΔU = q + w). Since internal energy is a state function, this combination does not represent a path function. - **(B) q**: Heat (q) is a path function because it depends on how the process is carried out (the path taken). - **(C) w**: Work (w) is also a path function for the same reason as heat; it depends on the path taken during the process. - **(D) H - TS**: This expression represents Gibbs free energy (G), which is a state function as it depends only on the initial and final states, not on the path taken. 3. **Conclusion**: - The parameters that represent path functions among the given options are **(B) q** and **(C) w**. ### Final Answer: The set of parameters that represents path functions is **(B) q and (C) w**.

To solve the question regarding which parameters represent path functions, we need to understand the concepts of state functions and path functions in thermodynamics. ### Step-by-Step Solution: 1. **Define State Functions and Path Functions**: - State functions depend only on the initial and final states of a system, regardless of the path taken to get there. Examples include internal energy (U), enthalpy (H), and Gibbs free energy (G). - Path functions depend on the specific path taken during a process. Examples include heat (q) and work (w). ...
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MODERN PUBLICATION-THERMODYNAMICS-Competition File MCQ
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  11. For the process H(2)O(l) to H(2)O(g) at T = 100^(@)C and 1 atmosphere ...

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  12. one mole of an ideal gas at 300k in thermal contact with surroundings ...

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  13. The standard state Gibbs free energies of formation of ) C(graphite an...

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  14. Which of the following are state functions?

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