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C(2)H(5)NH(2) + HNO(2) to A, A is :...

`C_(2)H_(5)NH_(2) + HNO_(2) to` A, A is :

A

`C_(2)H_(5)OH`

B

`C_(2)H_(5)NHOH`

C

`C_(2)H_(6)`

D

`C_(2)H_(5)NO_(2)`

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of ethylamine (C₂H₅NH₂) with nitrous acid (HNO₂), we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are ethylamine (C₂H₅NH₂) and nitrous acid (HNO₂). ### Step 2: Understand the Reaction When ethylamine reacts with nitrous acid, it forms an unstable compound known as ethyl diazonium salt (C₂H₅N₂⁺). This is a key intermediate in the reaction. ### Step 3: Formation of Ethyl Diazonium Salt The reaction can be represented as: \[ \text{C}_2\text{H}_5\text{NH}_2 + \text{HNO}_2 \rightarrow \text{C}_2\text{H}_5\text{N}_2^+ + \text{Cl}^- \] Here, the ethyl diazonium salt is formed, which is unstable. ### Step 4: Decomposition of Ethyl Diazonium Salt The ethyl diazonium salt is highly unstable and will decompose. The decomposition can be represented as: \[ \text{C}_2\text{H}_5\text{N}_2^+ \rightarrow \text{C}_2\text{H}_5\text{OH} + \text{N}_2 \uparrow \] During this step, the diazonium salt decomposes to produce ethanol (C₂H₅OH) and nitrogen gas (N₂). ### Step 5: Identify the Final Product The final product of the reaction is ethanol (C₂H₅OH). Therefore, the answer to the question is: **A is ethanol (C₂H₅OH).** ### Summary of the Reaction The overall reaction can be summarized as: \[ \text{C}_2\text{H}_5\text{NH}_2 + \text{HNO}_2 \rightarrow \text{C}_2\text{H}_5\text{OH} + \text{N}_2 \uparrow \]
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