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The dissociation energy of CH(4) and C(2...

The dissociation energy of `CH_(4) and C_(2)H_(6)` are respectively 1508 and `2594 kJ mol^(-1)` respectively. The bond energy of C-C bond is

A

`332 kJ mol^(-1)`

B

`316 kJ mol^(-1)`

C

`806 kJ mol^(-1)`

D

`320 kJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

For methane,
`4 Delta H_(C-H) = 1508 kJ`
:. `Delta H_(C-H) = (1508)/(4) = 377 kJ`
For dissociation of enthane, `H- underset(underset(H)(|))overset(overset(H)(|))(C) - underset(underset(H)(|))overset(overset(H)(|))(C)-H`
`Delta H_(C-H) + 6 Delta H_(C-H) = 2594 kJ`
`Delta H_(C-H) + 6 xx 377 = 2594`
`Delta H_(C-H) = 2594 - 6 xx 377`
= 332 kJ
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