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For complete combustion of ethanol, C(...

For complete combustion of ethanol,
`C_(2)H_(5)OH(l) + 3O_(2)(g) rarr 2CO_(2)(g) + 3H_(2)O(l)` the amount of heat produced as measured in bomb calorimeter is `1364.47 kJ mol^(-1)` at `25^(@)C`. Assuming ideality the enthalpy of comustion, `Delta_(c)H` for the reaction will be (`R = 8.314 kJ mol^(-1)`)

A

`- 1366.95 kJ mol^(-1)`

B

`- 1361.95 kJ mol^(-1)`

C

`- 1460.50 kJ mol^(-1)`

D

`- 1350.50 kJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

`C_(2)H_(5)OH(l) + 3O_(2)(g) rarr 2CO_(2)(g) + 3H_(2)O(l)`
`Delta n_(g) = 2 - 3 = - 1`
:. `Delta H = - 1364.47 + (1) xx 8.314 xx 10^(-3) xx 298`
`= - 1366.93 kJ mol^(-1)`
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