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A 0.5 molal solution of ethylene glycol ...

A 0.5 molal solution of ethylene glycol in water is used as coolant in a car. If the freezing point constant of water be `1.86^(@)C` per mol, the mixture will freeze at

A

`0.93^(@)C`

B

`-0.93^(@)C`

C

`1.86^(@)C`

D

`-1.86^(@)C`

Text Solution

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The correct Answer is:
B
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A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9 Given: Freezing point depression constant of water (K_(f)^(water)=1.86 K kg mol^(-1)) Freezing point depression constant to ethanol (K_(f)^(ethanol))=2.0 K kg mol^(-1)) Boiling point elevation constant of water (K_(b)^(water))=0.52 K kg mol^(-1)) Boiling point elevation constant of ethanol (K_(b)^(ethanol))=1.2 K kg mol^(-1)) Standard freezing point of water = 273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water = 373 K Standard boiling point of ethanol = 351.5 K Vapour pressure of pure water = 32.8 mm Hg Vapour pressure of pure ethanol = 40 mm Hg Molecular weight of water = 18 g mol^(-1) Molecular weight of ethanol = 46 g mol^(-1) In anwering the following questions consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. The freezing point of the solution M is

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In a 0.2 molal aqueous solution of a weal acid, HX, the degree of dissociation is 0.3 . Taking K_(f) for water as 1.85, the freezing point of the solution will be nearest to

MODERN PUBLICATION-SOLUTIONS-Multiple Choice Questions (Level-I) (Basic conceptual Qs) (Colligative Properties)
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