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Excess of PCl(5) reacts with conc. H(2)S...

Excess of `PCl_(5)` reacts with conc. `H_(2)SO_(4)` giving

A

Chlorosulphuric acid

B

Sulphurous acid

C

Sulphurous chloride

D

sulfuryl chloride

Text Solution

Verified by Experts

The correct Answer is:
C

`H_(2)SO_(4)overset(PCl_(5))rarr HOSO_(2)Cloverset(PCl_(5))rarr SO_(2)Cl_(2)`
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MODERN PUBLICATION-CHEMISTRY OF P - BLOCK ELEMENTS-Multiple Choice Questions (Level - II) (Comprehensive Qs)
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  3. Excess of PCl(5) reacts with conc. H(2)SO(4) giving

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  4. The oxoacid of sulphur that contains a lone pair of electrons on sulph...

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  5. The correct order of acidic stength is :

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  6. The number of sigma - bonds in P4O(10) is :

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  7. H(3)BO(3) is :

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  8. Among Al(2)O(3), SiO(2),P(2)O(3) and SO(2), the correct order of acid ...

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  9. The correct order of bond angle (smallest first) in H(2)S, NH(3), BF(3...

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  10. Which one of the following has the regular tetrahedral structure ?

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  11. The number of hydrogen atoms attached to phsophorus atom in hypophosph...

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  12. The correct order of thermal stability of hydrogen halides (H-X) is :

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  13. In silicon dioxide:

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  14. The structure of dibroane (B(2)H(6)) contains :

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  15. Which reaction indicates the oxidising behaviour of H(2) SO(4)

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  16. A metal M forms chlorides in its +2 and +4 oxidation states. Which of ...

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  17. Which of the following statement is true?

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  18. In which of the following molecules / ions are all the bonds not equal...

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  19. The decreasing order of bond angles from NH(3) (106^(@)) to SbH(3)(101...

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  20. A colourless aqueous solution on adding water and on heating gave a wh...

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