Write expression for Boyle's temperature and critical temperature in terms of van der Waals constants. Which one is larger for a particular gas?

Explanation

To solve the question regarding the expressions for Boyle's temperature and critical temperature in terms of van der Waals constants, we will follow these steps:

### Step 1: Define Boyle's Temperature
Boyle's temperature (Tb) is defined as the temperature at which a real gas behaves ideally over a wide range of pressures. The expression for Boyle's temperature in terms of van der Waals constants is given by:

\[ T_b = \frac{A}{B \cdot R} \]

where:
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