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C(6)H(5)CH(2)CH(2)CH(3) is when oxidised...

`C_(6)H_(5)CH_(2)CH_(2)CH_(3)` is when oxidised in the presence of alk. `KMnO_(4)` the product obtained is

A

`C_(6)H_(5)CHO`

B

`C_(6)H_(5)COOH`

C

`C_(6)H_(5)CH_(2)CH_(2)CHO`

D

`C_(6)H_(5)COCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the product formed when the compound \( C_6H_5CH_2CH_2CH_3 \) (which can be represented as a phenylpropyl group) is oxidized in the presence of alkaline \( KMnO_4 \). ### Step-by-Step Solution: 1. **Identify the Structure of the Compound**: The compound \( C_6H_5CH_2CH_2CH_3 \) consists of a benzene ring (C6H5) attached to a propyl group (CH2CH2CH3). This means it has a total of 6 carbons in the benzene and 3 in the propyl group, making a total of 9 carbons. 2. **Understand the Oxidation Process**: Alkaline \( KMnO_4 \) is a strong oxidizing agent. It can oxidize alkyl side chains attached to aromatic rings. In this case, it will oxidize the propyl group (the alkyl chain) completely. 3. **Complete Oxidation of the Alkyl Chain**: The propyl group (CH2CH2CH3) will be oxidized to form a carboxylic acid. Since the propyl group has 3 carbons, the complete oxidation will convert each carbon in the alkyl chain into a carboxylic acid group (-COOH). 4. **Formation of the Product**: The oxidation of the propyl group will yield: - The terminal carbon (C1) will be oxidized to a carboxylic acid (-COOH). - The other two carbons (C2 and C3) will also be oxidized to form a carboxylic acid. Therefore, the entire propyl group will be converted into a carboxylic acid, resulting in the formation of benzoic acid (C6H5COOH). 5. **Final Product**: The final product obtained after the oxidation of \( C_6H_5CH_2CH_2CH_3 \) in the presence of alkaline \( KMnO_4 \) is benzoic acid (C6H5COOH). ### Conclusion: The product obtained from the oxidation of \( C_6H_5CH_2CH_2CH_3 \) with alkaline \( KMnO_4 \) is **benzoic acid**. ---
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