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(CH(3))(3)C CH(2)COOH is more acidic tha...

`(CH_(3))_(3)C CH_(2)COOH` is more acidic than `(CH_(3))_(3)SiCH_(2)COOH` because

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Silican is electropostive than carbon and therefore has more electron donating effect .

As a result the anion `Me_3Si CH_2 COO ` ( conjugate base ) becomes less stable than `Me_3 C CH_2 COO^(-)` thus `Me_2C CH_2COOH` is more acidic than ` Me_3 SiCH_2 COOH `
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CH_(3)CH(OH)CH_(2)CH_(2)COOH

Me_3 C CH_2 COOH is more acidic than Me_3 SiCH_2 COOH.

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The systematic name of (CH_(3))_(2)CH-COOH

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(a) Account for the following : (i) Cl-CH_(2)COOH is a stronger acid than CH_(3)COOH (ii) Carboxylic acids do not give reaction of carbonyl group (b) write the chemical equation to illustrate the following name reactions: (i) Rosenmund reduction (ii) Cannizzaro 's reaction (C ) Out of CH_(3)CH_(2)-CO-CH_(2)-CH_(3) and CH_(3)CH_(2)-CH_(2)-CO-CH_(3) which gives iodoform test?