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In the carbonyl group, the carbon atom u...

In the carbonyl group, the carbon atom undergoes

A

sp hybridisation

B

`sp^2` hybridisation

C

`sp^3` hybridisation

D

`sp^3 `d hybridisation.

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The correct Answer is:
To determine the hybridization of the carbon atom in the carbonyl group (C=O), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure**: The carbonyl group consists of a carbon atom double-bonded to an oxygen atom (C=O). The general structure can be represented as R-C(=O)-R', where R and R' are hydrocarbon groups or hydrogen atoms. 2. **Count the Sigma Bonds**: - In the carbonyl group, the carbon atom forms: - 1 sigma bond with the oxygen atom (C=O). - 1 sigma bond with the R group (R-C). - 1 sigma bond with the R' group (C-R'). - Therefore, the total number of sigma bonds is 3. 3. **Consider Lone Pairs and Charges**: - In the carbonyl group, the carbon atom does not have any lone pairs or formal charges. - Thus, we do not add any additional counts for lone pairs or charges. 4. **Calculate the Steric Number**: - The steric number is calculated as the sum of sigma bonds, lone pairs, and negative charges. - Here, we have 3 sigma bonds, 0 lone pairs, and 0 charges. - Steric number = 3 + 0 + 0 = 3. 5. **Determine the Hybridization**: - Based on the steric number: - If the steric number is 2, the hybridization is sp (linear geometry). - If the steric number is 3, the hybridization is sp² (trigonal planar geometry). - If the steric number is 4, the hybridization is sp³ (tetrahedral geometry). - Since the steric number is 3, the hybridization of the carbon atom in the carbonyl group is sp². ### Final Answer: The hybridization of the carbon atom in the carbonyl group is **sp²**.
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MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-REVISION EXERCISES (OBJECTIVE QUESTIONS - MULTIPLE CHOICE QUESTIONS )
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  10. Salicylic acid on heating with soda lime gives

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  12. Carboxylic acids are reduced by red P and HI to

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  14. Which of the following compounds does not have a carboxyl group ?

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  15. The conversion of a carboxylic acid to alpha-bromocarboxylic acid usin...

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  16. RCOOAg+Br(2)overset(C C1(4))underset(Delta)rarrR-Br+AgBr+CO(2) this re...

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  18. Decarboxylation of sodium benzoate on heating with soda lime gives

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  19. Benzoic acid reacts with LiAIH4 to give

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  20. The IUPAC name of the compound CH3 -CH2 - overset(O ) overset(||)C-...

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