Home
Class 12
CHEMISTRY
Which of the following gives iodoform te...

Which of the following gives iodoform test?

A

`CH_3 OH `

B

`CH_3 COCH_2CH_3`

C

`HCHO`

D

`CH_3 COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds gives a positive iodoform test, we need to understand the conditions under which this test is positive. The iodoform test is typically positive for compounds that contain a methyl ketone group (RCOCH3) or a secondary alcohol that can be oxidized to a methyl ketone. ### Step-by-Step Solution: 1. **Understand the Iodoform Test**: The iodoform test involves the reaction of a compound with iodine (I2) in the presence of a base (usually sodium hydroxide, NaOH). The key requirement for a compound to give a positive iodoform test is the presence of a methyl group adjacent to a carbonyl group (C=O) or a secondary alcohol that can be oxidized to a methyl ketone. 2. **Identify the Functional Groups**: Check the given options for the presence of the functional groups: - Methyl ketone (RCOCH3) - Secondary alcohol (RCHOHCH3) 3. **Analyze Each Compound**: - **Compound A**: Check if it has a methyl ketone or can be oxidized to one. - **Compound B**: Check if it has a methyl ketone or can be oxidized to one. - **Compound C**: Check if it has a methyl ketone or can be oxidized to one. - **Compound D**: Check if it has a methyl ketone or can be oxidized to one. 4. **Determine the Result**: - If any of the compounds contain the methyl ketone structure (RCOCH3) or can be oxidized to form such a structure from a secondary alcohol, they will give a positive iodoform test. - If none of the compounds meet these criteria, they will not give a positive iodoform test. 5. **Conclusion**: Based on the analysis, identify which compound(s) give a positive iodoform test.

To determine which of the given compounds gives a positive iodoform test, we need to understand the conditions under which this test is positive. The iodoform test is typically positive for compounds that contain a methyl ketone group (RCOCH3) or a secondary alcohol that can be oxidized to a methyl ketone. ### Step-by-Step Solution: 1. **Understand the Iodoform Test**: The iodoform test involves the reaction of a compound with iodine (I2) in the presence of a base (usually sodium hydroxide, NaOH). The key requirement for a compound to give a positive iodoform test is the presence of a methyl group adjacent to a carbonyl group (C=O) or a secondary alcohol that can be oxidized to a methyl ketone. 2. **Identify the Functional Groups**: ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS

    MODERN PUBLICATION|Exercise REVISION EXERCISES (OBJECTIVE QUESTIONS - PASSAGE BASED QUESTIONS )|10 Videos
  • ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS

    MODERN PUBLICATION|Exercise REVISION EXERCISES (OBJECTIVE QUESTIONS - ASSERTION REASON QUESTIONS )|10 Videos
  • ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS

    MODERN PUBLICATION|Exercise QUICK MEMORY TEST ( C. CHOOSE THE CORRECT ALTERNATIVE )|19 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST (FOR BOARD EXAMINATION)|12 Videos
  • BIOMOLECULES

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST FOR BOARD EXAMINATION|13 Videos

Similar Questions

Explore conceptually related problems

Which of the following give(s) iodoform test? Give their oxidation products after acidification.

Which of the following can give iodoform test ?

Which one of the following gives iodoform test?

Which one of the following gives iodoform test?

Which of the following will give iodoform test?

Which of the following will give iodoform test?

Which of the following give positive iodoform test ? (1) Ethanol, (2) Ethanal (3) Butan-1-ol, (4) Butan-2-ol (5) Phenyl ethanol.

MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-REVISION EXERCISES (OBJECTIVE QUESTIONS - MULTIPLE CHOICE QUESTIONS )
  1. In the carbonyl group, the carbon atom undergoes

    Text Solution

    |

  2. CH3 COCl underset(BaSO4) overset(Pd,H2) to X,X is

    Text Solution

    |

  3. Which of the following gives iodoform test?

    Text Solution

    |

  4. The reaction of formaldehyde with methyl magnesium bromide followed by...

    Text Solution

    |

  5. Which of the following will not undergo aldol condensation?

    Text Solution

    |

  6. Which of the following is the strongest acid ?

    Text Solution

    |

  7. Vinegar is dilute aqueous solution of

    Text Solution

    |

  8. Salicylic acid on heating with soda lime gives

    Text Solution

    |

  9. The strongest acid among the following is

    Text Solution

    |

  10. Carboxylic acids are reduced by red P and HI to

    Text Solution

    |

  11. Formic acid and acetic acid are distinguished by

    Text Solution

    |

  12. Which of the following compounds does not have a carboxyl group ?

    Text Solution

    |

  13. The conversion of a carboxylic acid to alpha-bromocarboxylic acid usin...

    Text Solution

    |

  14. RCOOAg+Br(2)overset(C C1(4))underset(Delta)rarrR-Br+AgBr+CO(2) this re...

    Text Solution

    |

  15. Benzene reacts with CH(3)COCl in the presence of anhy AlCl(3) to give

    Text Solution

    |

  16. Decarboxylation of sodium benzoate on heating with soda lime gives

    Text Solution

    |

  17. Benzoic acid reacts with LiAIH4 to give

    Text Solution

    |

  18. The IUPAC name of the compound CH3 -CH2 - overset(O ) overset(||)C-...

    Text Solution

    |

  19. Which is most acidic ?

    Text Solution

    |

  20. Among the following which has lowest pKa value?

    Text Solution

    |