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Which of the following will not undergo ...

Which of the following will not undergo aldol condensation?

A

Acetaldehyde

B

Propanaldehyde

C

Benzaldehyde

D

Propanone

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The correct Answer is:
To determine which compound will not undergo aldol condensation, we need to analyze the provided options based on the criteria for aldol condensation reactions. Here’s a step-by-step solution: ### Step 1: Understand Aldol Condensation Aldol condensation is a reaction that occurs between aldehydes or ketones that have at least one alpha hydrogen. An alpha hydrogen is a hydrogen atom attached to the carbon adjacent to the carbonyl group (C=O). ### Step 2: Identify the Options Let’s assume the options are: - A: Acetaldehyde (CH3CHO) - B: Propanal (CH3CH2CHO) - C: Benzaldehyde (C6H5CHO) - D: Acetone (CH3COCH3) ### Step 3: Analyze Each Compound 1. **Acetaldehyde (A)**: - Structure: CH3CHO - Alpha Carbon: The carbon next to the carbonyl (C=O) is CH3, which has 3 alpha hydrogens. - Conclusion: Can undergo aldol condensation. 2. **Propanal (B)**: - Structure: CH3CH2CHO - Alpha Carbon: The carbon next to the carbonyl (C=O) is CH2, which has 2 alpha hydrogens. - Conclusion: Can undergo aldol condensation. 3. **Benzaldehyde (C)**: - Structure: C6H5CHO - Alpha Carbon: The carbon next to the carbonyl is part of the benzene ring and has no hydrogen atoms attached (the carbon is fully substituted). - Conclusion: Cannot undergo aldol condensation. 4. **Acetone (D)**: - Structure: CH3COCH3 - Alpha Carbon: The carbons next to the carbonyl (C=O) are both CH3, each having 3 alpha hydrogens. - Conclusion: Can undergo aldol condensation. ### Step 4: Identify the Answer Based on the analysis, the compound that will not undergo aldol condensation is **C: Benzaldehyde**. ### Final Answer **C: Benzaldehyde will not undergo aldol condensation.** ---
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MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-REVISION EXERCISES (OBJECTIVE QUESTIONS - MULTIPLE CHOICE QUESTIONS )
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  2. The reaction of formaldehyde with methyl magnesium bromide followed by...

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  3. Which of the following will not undergo aldol condensation?

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  4. Which of the following is the strongest acid ?

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  5. Vinegar is dilute aqueous solution of

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  6. Salicylic acid on heating with soda lime gives

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  7. The strongest acid among the following is

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  8. Carboxylic acids are reduced by red P and HI to

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  9. Formic acid and acetic acid are distinguished by

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  10. Which of the following compounds does not have a carboxyl group ?

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  11. The conversion of a carboxylic acid to alpha-bromocarboxylic acid usin...

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  12. RCOOAg+Br(2)overset(C C1(4))underset(Delta)rarrR-Br+AgBr+CO(2) this re...

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  13. Benzene reacts with CH(3)COCl in the presence of anhy AlCl(3) to give

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  14. Decarboxylation of sodium benzoate on heating with soda lime gives

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  15. Benzoic acid reacts with LiAIH4 to give

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  16. The IUPAC name of the compound CH3 -CH2 - overset(O ) overset(||)C-...

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  17. Which is most acidic ?

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  18. Among the following which has lowest pKa value?

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  19. The IUPAC name of CH3 CH2 - overset(O ) overset(||)C-CH2-overset...

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  20. What is the name of the following reaction:

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