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In the following, strongest acid is :...

In the following, strongest acid is :

A

`CH_3CH_2COOH`

B

`CH_3COOH `

C

`C_6 H_5 COOH `

D

`C_6H_5CH_2COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds is the strongest acid, we need to analyze how well each compound can donate a proton (H+) and how the resulting negative charge (conjugate base) can be stabilized. Here’s a step-by-step solution: ### Step 1: Identify the Compounds First, we need to identify the four compounds given in the question. Let's assume they are: 1. Compound A 2. Compound B 3. Compound C 4. Compound D ### Step 2: Understand Acid Strength The strength of an acid is determined by its ability to donate a proton (H+). When an acid donates a proton, it forms a conjugate base. The stability of this conjugate base is crucial; the more stable the conjugate base, the stronger the acid. ### Step 3: Analyze the Conjugate Bases For each compound, we will analyze the structure of the conjugate base formed after the proton is lost. - **Compound A**: After losing H+, the conjugate base will have a negative charge that may not be well stabilized. - **Compound B**: Similar analysis as Compound A. - **Compound C**: The conjugate base formed here will have a negative charge that can be stabilized by resonance or inductive effects. - **Compound D**: The conjugate base may also have some stabilization, but it is less effective than in Compound C. ### Step 4: Evaluate Stabilization Effects - **Inductive Effect**: The presence of electronegative atoms or groups can stabilize the negative charge through the inductive effect. - **Resonance Effect**: If the negative charge can delocalize through resonance, this will significantly stabilize the conjugate base. ### Step 5: Compare the Compounds - **Compound C**: If it has a phenyl group attached to the carboxyl group, the negative charge on the conjugate base can be stabilized by resonance with the phenyl ring, making it more stable. - **Compound D**: If it lacks the resonance stabilization or has less effective inductive effects compared to Compound C, it will be a weaker acid. ### Conclusion After analyzing all compounds, we conclude that **Compound C** is the strongest acid due to the resonance stabilization of its conjugate base.
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Knowledge Check

  • Which of the following strongest acid in the following?

    A
    `HCIO_(3)`
    B
    `HCIO_(4)`
    C
    `H_(2)SO_(3)`
    D
    `H_(2)SO_(4)`
  • Among the following the strongest acid is

    A
    `CH_3COOH`
    B
    `C_6H_5COOH`
    C
    `m - CH_3OC_6H_4COOH`
    D
    `p - CH_3OC_6H_4COOH`
  • Among the following the strongest acid is

    A
    `CH_(3) COOH`
    B
    `CH_(2) ClCH_(2)COOH`
    C
    `CH_(2)ClCOOH`
    D
    `CH_(3)CH_(2) COOH`
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