Home
Class 12
CHEMISTRY
In the reaction HC -= CH underse...

In the reaction
` HC -= CH underset( "dil" H_2 SO_4 ) overset( Hg SO_4) to X overset(LIAIH _4 ) to Y overset(P, Br_2) to Z,` Z is

A

Ethylidene bromide

B

Ehtyl bromide

C

Bromobenzene

D

Ehtylene bromide

Text Solution

AI Generated Solution

The correct Answer is:
To determine the compound Z in the given reaction sequence, we will break down each step of the reaction process. ### Step 1: Reaction of Acetylene with Dilute H2SO4 and HgSO4 - We start with acetylene (HC≡CH). - When acetylene reacts with dilute sulfuric acid (H2SO4) in the presence of mercuric sulfate (HgSO4), it undergoes hydration. - According to Markovnikov's rule, water (H2O) adds across the triple bond, resulting in the formation of acetaldehyde (CH3CHO). - **X = CH3CHO (Acetaldehyde)** ### Step 2: Reduction of Acetaldehyde with LiAlH4 - The next step involves the reduction of acetaldehyde (X) using lithium aluminum hydride (LiAlH4). - LiAlH4 is a strong reducing agent that reduces aldehydes to primary alcohols. - The reaction converts acetaldehyde (CH3CHO) to ethanol (CH3CH2OH). - **Y = CH3CH2OH (Ethanol)** ### Step 3: Reaction of Ethanol with PBr2 - The final step involves the reaction of ethanol (Y) with phosphorus tribromide (PBr2). - Ethanol is a primary alcohol, and when it reacts with PBr2, it undergoes an SN2 reaction mechanism. - In this reaction, the hydroxyl group (OH) is replaced by a bromine atom (Br), resulting in the formation of bromoethane (CH3CH2Br). - **Z = CH3CH2Br (Bromoethane)** ### Final Answer Thus, the compound Z is **Bromoethane (CH3CH2Br)**. ---

To determine the compound Z in the given reaction sequence, we will break down each step of the reaction process. ### Step 1: Reaction of Acetylene with Dilute H2SO4 and HgSO4 - We start with acetylene (HC≡CH). - When acetylene reacts with dilute sulfuric acid (H2SO4) in the presence of mercuric sulfate (HgSO4), it undergoes hydration. - According to Markovnikov's rule, water (H2O) adds across the triple bond, resulting in the formation of acetaldehyde (CH3CHO). - **X = CH3CHO (Acetaldehyde)** ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS

    MODERN PUBLICATION|Exercise COMPETITION FILE ( OBJECTIVE TYPE QUESTIONS - MULTIPLE CHOICE QUESTIONS (MCQ) ( B. MULTIPLE CHOICE QUESTIONS )|86 Videos
  • ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS

    MODERN PUBLICATION|Exercise COMPETITION FILE ( OBJECTIVE TYPE QUESTIONS - MULTIPLE CHOICE QUESTIONS (MCQ) ( C. MULTIPLE CHOICE QUESTIONS )|10 Videos
  • ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS

    MODERN PUBLICATION|Exercise HOTS HIGHER ORDER THINKING SKILLS|15 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST (FOR BOARD EXAMINATION)|12 Videos
  • BIOMOLECULES

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST FOR BOARD EXAMINATION|13 Videos

Similar Questions

Explore conceptually related problems

Identity A,B and C in the following reaction HC-=CH underset(HgSO_(4)) overset(dil.H_(2)SO_(4))toA overset(dil.NaOH)toB overset(heat)toC

Identify A, B and C in the following reaction: CH-=CH underset(HgSO_(4))overset("dil. "H_(2)SO_(4))to A overset("dil. "NaOH)toBoverset("heat")to C

Knowledge Check

  • CH-=Chunderset(H_2SO_4)overset(H_2O // Hg^(2+))to X overset(LiAIH_4)to Y overset(P_4//Br_2)to Z Here Z is

    A
    Ethylene bromide
    B
    Ethanol
    C
    Ethyl bromide
    D
    Ethylidene bromide
  • CH-=CH underset(H_2SO_4)overset(HgSO_4)to underset(H_2O)overset(CH_3MgBr)to overset(P//Br_2)to

    A
    `CH_3CH(Br)CH_3`
    B
    `CH_3CH_2CH_2Br`
    C
    `CH_2=CH-Br`
    D
    `BrCH=CH-CH_3`
  • In the reaction : HC -= CH overset(NaNH_(2)) to overset(CH_(3)I)to Y underset(H^(+))overset(H_(2)O, HG^(2+))to Z ,

    A
    `CH_(3)CHO`
    B
    `CH_(3)CH_(2)CH=CH_(2)`
    C
    `CH_(3)COCH_(3)`
    D
    `CH_(3)CH_(2)CHO`
  • Similar Questions

    Explore conceptually related problems

    In the following reaction HC-=CH underset(Hg^(2+))overset(H_2SO_4)to 'P' Product 'P' will not give

    (A)underset("dil."H_(2)SO_(4))overset(HgSO_(4))(to)(B)overset(LiAlH_(4))(to) underset("recemic mixture")((C)) therefore reactant (A) is :

    CH-=CH underset(dil.H_(2)SO_(4))overset(Hg^(2+))toAunderset(HCl)overset(Zn-Hg)toB B is

    HC-=CHunderset(H_(2)SO_(4))overset(HgSO_(4))rarr overset(CH_(3)CH_(2)CH_(2)Br)rarr overset(PBr_(3))rarr

    CH-=Chunderset(H_(2)SO_(4))overset(HgSO_(4))(to)(X)overset(LiAlH_(4))(to)(Y) In this sequence of reaction (Y) is,