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In the reaction HC -= CH underse...

In the reaction
` HC -= CH underset( "dil" H_2 SO_4 ) overset( Hg SO_4) to X overset(LIAIH _4 ) to Y overset(P, Br_2) to Z,` Z is

A

Ethylidene bromide

B

Ehtyl bromide

C

Bromobenzene

D

Ehtylene bromide

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The correct Answer is:
To determine the compound Z in the given reaction sequence, we will break down each step of the reaction process. ### Step 1: Reaction of Acetylene with Dilute H2SO4 and HgSO4 - We start with acetylene (HC≡CH). - When acetylene reacts with dilute sulfuric acid (H2SO4) in the presence of mercuric sulfate (HgSO4), it undergoes hydration. - According to Markovnikov's rule, water (H2O) adds across the triple bond, resulting in the formation of acetaldehyde (CH3CHO). - **X = CH3CHO (Acetaldehyde)** ### Step 2: Reduction of Acetaldehyde with LiAlH4 - The next step involves the reduction of acetaldehyde (X) using lithium aluminum hydride (LiAlH4). - LiAlH4 is a strong reducing agent that reduces aldehydes to primary alcohols. - The reaction converts acetaldehyde (CH3CHO) to ethanol (CH3CH2OH). - **Y = CH3CH2OH (Ethanol)** ### Step 3: Reaction of Ethanol with PBr2 - The final step involves the reaction of ethanol (Y) with phosphorus tribromide (PBr2). - Ethanol is a primary alcohol, and when it reacts with PBr2, it undergoes an SN2 reaction mechanism. - In this reaction, the hydroxyl group (OH) is replaced by a bromine atom (Br), resulting in the formation of bromoethane (CH3CH2Br). - **Z = CH3CH2Br (Bromoethane)** ### Final Answer Thus, the compound Z is **Bromoethane (CH3CH2Br)**. ---

To determine the compound Z in the given reaction sequence, we will break down each step of the reaction process. ### Step 1: Reaction of Acetylene with Dilute H2SO4 and HgSO4 - We start with acetylene (HC≡CH). - When acetylene reacts with dilute sulfuric acid (H2SO4) in the presence of mercuric sulfate (HgSO4), it undergoes hydration. - According to Markovnikov's rule, water (H2O) adds across the triple bond, resulting in the formation of acetaldehyde (CH3CHO). - **X = CH3CHO (Acetaldehyde)** ...
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