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When C6 H5 COCOC6 H5 is reduced with LiA...

When `C_6 H_5 COCOC_6 H_5` is reduced with `LiAlH_4`, the product formed has ________stereoisomers.

A

2

B

3

C

4

D

6

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The correct Answer is:
To determine the number of stereoisomers formed when \( C_6H_5COCOC_6H_5 \) is reduced with \( LiAlH_4 \), we can follow these steps: ### Step 1: Identify the Structure The compound \( C_6H_5COCOC_6H_5 \) has the following structure: - It consists of two phenyl groups (\( C_6H_5 \)) connected by a carbon chain that contains two carbonyl groups (C=O). - The structure can be represented as \( C_6H_5-CO-CO-C_6H_5 \). ### Step 2: Reduction with \( LiAlH_4 \) When this compound is reduced with \( LiAlH_4 \), a strong reducing agent, both carbonyl groups (C=O) will be reduced to hydroxyl groups (–OH), resulting in the formation of a diol: - The product will be \( C_6H_5-CHOH-CHOH-C_6H_5 \). ### Step 3: Analyze the Product for Chirality Next, we need to analyze the product for chiral centers: - The two hydroxyl groups are attached to the central carbon atoms, which can potentially create chiral centers. - Each of the two central carbon atoms (where the –OH groups are attached) can have four different substituents, making them chiral centers. ### Step 4: Count the Chiral Centers In the product \( C_6H_5-CHOH-CHOH-C_6H_5 \): - There are **two chiral centers** (the two carbon atoms bonded to the –OH groups). ### Step 5: Calculate the Number of Stereoisomers To find the number of stereoisomers, we can use the formula: \[ \text{Number of stereoisomers} = 2^n \] where \( n \) is the number of chiral centers. - Here, \( n = 2 \), so: \[ \text{Number of stereoisomers} = 2^2 = 4 \] ### Conclusion Thus, the product formed when \( C_6H_5COCOC_6H_5 \) is reduced with \( LiAlH_4 \) has **4 stereoisomers**. ---

To determine the number of stereoisomers formed when \( C_6H_5COCOC_6H_5 \) is reduced with \( LiAlH_4 \), we can follow these steps: ### Step 1: Identify the Structure The compound \( C_6H_5COCOC_6H_5 \) has the following structure: - It consists of two phenyl groups (\( C_6H_5 \)) connected by a carbon chain that contains two carbonyl groups (C=O). - The structure can be represented as \( C_6H_5-CO-CO-C_6H_5 \). ...
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