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Glucose reacts with Tollen's reagent to ...

Glucose reacts with Tollen's reagent to give a derivative of

A

monocarboxylic acid

B

dicarboxylic acid

C

ketone

D

keto acid

Text Solution

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The correct Answer is:
To solve the question of what derivative glucose gives when it reacts with Tollen's reagent, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Glucose**: - Glucose is an aldohexose, meaning it contains an aldehyde group (-CHO) and has six carbon atoms. The open-chain structure of glucose can be represented as: ``` CHO - (CHOH)4 - CH2OH ``` 2. **Understand Tollen's Reagent**: - Tollen's reagent is a solution of silver nitrate (AgNO3) in ammonia (NH3) that contains the complex ion [Ag(NH3)2]+. It is used to oxidize aldehydes to carboxylic acids. 3. **Reaction Mechanism**: - When glucose reacts with Tollen's reagent, the aldehyde group (-CHO) of glucose is oxidized to a carboxylic acid group (-COOH). The reaction can be summarized as: ``` CHO (from glucose) + [Ag(NH3)2]+ → COOH (carboxylic acid) + Ag (silver precipitate) ``` 4. **Product Formation**: - The product formed from the oxidation of glucose will be gluconic acid, which has the structure: ``` HOOC - (CHOH)4 - CH2OH ``` 5. **Identify the Type of Derivative**: - The product, gluconic acid, contains one carboxylic acid group, making it a monocarboxylic acid. Therefore, the derivative formed from glucose upon reaction with Tollen's reagent is a derivative of a monocarboxylic acid. ### Final Answer: The derivative of glucose when it reacts with Tollen's reagent is a **derivative of monocarboxylic acid**. ---

To solve the question of what derivative glucose gives when it reacts with Tollen's reagent, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Glucose**: - Glucose is an aldohexose, meaning it contains an aldehyde group (-CHO) and has six carbon atoms. The open-chain structure of glucose can be represented as: ``` CHO - (CHOH)4 - CH2OH ...
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