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In hydrogen atomic spectrum , a series ...

In hydrogen atomic spectrum , a series limit is found at `12186.3 cm^(-1)`. Then it belong to :

A

Lyman series

B

Balmer series

C

Paschen series

D

Bracket series

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The correct Answer is:
To determine which series the series limit of 12186.3 cm^(-1) belongs to in the hydrogen atomic spectrum, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Series Limit**: The series limit refers to the highest energy transition in a series, which occurs when an electron transitions from a higher energy level (n2) to a lower energy level (n1). In this case, the series limit corresponds to n2 approaching infinity. 2. **Using the Rydberg Formula**: The Rydberg formula for the hydrogen spectrum is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R_H \) is the Rydberg constant (approximately \( 109677 \, \text{cm}^{-1} \)), \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level. 3. **Setting Up the Equation**: For the series limit, we set \( n_2 = \infty \). Thus, the equation simplifies to: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - 0 \right) \] This means: \[ \frac{1}{\lambda} = \frac{R_H}{n_1^2} \] 4. **Substituting the Given Value**: We know that \( \frac{1}{\lambda} = 12186.3 \, \text{cm}^{-1} \). Now substitute this into the equation: \[ 12186.3 = \frac{109677}{n_1^2} \] 5. **Solving for \( n_1 \)**: Rearranging gives: \[ n_1^2 = \frac{109677}{12186.3} \] Calculating this: \[ n_1^2 \approx 9.0 \quad \Rightarrow \quad n_1 \approx 3 \] 6. **Identifying the Series**: Now that we have \( n_1 = 3 \), we can identify the series: - Lyman series: \( n_1 = 1 \) - Balmer series: \( n_1 = 2 \) - Paschen series: \( n_1 = 3 \) - Brackett series: \( n_1 = 4 \) Since \( n_1 = 3 \), this corresponds to the Paschen series. ### Conclusion: The series limit at \( 12186.3 \, \text{cm}^{-1} \) belongs to the **Paschen series**.

To determine which series the series limit of 12186.3 cm^(-1) belongs to in the hydrogen atomic spectrum, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Series Limit**: The series limit refers to the highest energy transition in a series, which occurs when an electron transitions from a higher energy level (n2) to a lower energy level (n1). In this case, the series limit corresponds to n2 approaching infinity. 2. **Using the Rydberg Formula**: ...
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