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In which of the following pairs both the...

In which of the following pairs both the complex show optical isomerism? .

A

cis `-[Cr(C_2 O_4)_2 Cl_2]^(2-) " ""cis"[Co(NH_3)_4 Cl_2]`

B

`[Co("en")_3]Cl_3, " ""cis"-[Co("en")_2 Cl_2 ]Cl`

C

`[Co(NO_3)_3 (NH_3)_3], " ""cis" -[Pt("en")_2Cl_2]`

D

`[PtCl("en")Cl] , " "[NiCl_2Br_2]^(2-)`

Text Solution

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The correct Answer is:
B
`[Co("en")_3]Cl_3, " ""cis"-[Co("en")_2 Cl_2 ]Cl`
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DISHA PUBLICATION-COORDINATION COMPOUNDS -Exercise
  1. Which statement about coordination number of a cation is true?

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  2. Select the correct code about complex [Cr(NO(2))(NH(3))(5)][ZnCl(4)] :...

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  3. In which of the following pairs both the complex show optical isomeris...

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  4. The total number possible isomers for the complex compound [Cu^(II)(NH...

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  5. Which of the following will give maximum number of isomer ?

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  6. Which of the following compounds shows optical isomerism?

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  7. The ionisation isomer of [Cr(H(2)O)(4) Cl (NO(2))]Cl

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  8. The correct structure of ethylenediamineteraacetic acid (EDTA) is .

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  9. Which one of the following complex is not expected to exhibit isomeris...

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  10. The complexes [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] are the ex...

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  11. The complex, [Pt(py)(NH3)BrCl] will have how many geometrical isomers?

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  12. The sum of coordination number and oxidation number of the metal M in ...

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  13. Which of the following is the most likely structure of CrCl3*6H2O, if ...

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  14. Which of the following is not chelating agent (a) Thiosulphate (b)...

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  15. Which of the following species is not expected to be a ligand?

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  16. Which is the pair of ambidentate ligand?

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  17. Number of water molecules acting as ligands in CuSO(4).5H(2)O,ZnSO(4...

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  18. Which of the following pair of complexes have the same EAN of the cent...

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  20. In octaamine -mu-dihydroxodiiron(III)sulphate, the number of bridging ...

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