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the correct IUPAC name of the following ...

the correct IUPAC name of the following compound `[Cr(NH_3)_5(NCS)][ZnCl_4]` is

A

colourless and diamagnetic

B

green coloured and diamagnetic

C

green coloured and shows coordination isomerism

D

diamagnetic and shows linkage isomerism

Text Solution

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The correct Answer is:
C

Due to the cationic part of the complex, it is green, because there are three unpaired electrons in `t_(2g)` orbitals of `Cr^(3+)` cation, both cationic and anionic parts are complex ions, hence, coordination isomerism will be exhibited by it.
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DISHA PUBLICATION-COORDINATION COMPOUNDS -Exercise
  1. Relative to the average energy in the spherical crystal field the t(2g...

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  2. Which of the following outer orbital complex has the highest magnetic ...

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  3. the correct IUPAC name of the following compound [Cr(NH3)5(NCS)][ZnCl4...

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  4. Mn^(2+) forms a complex with Br– ion. The magnetic moment of the compl...

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  5. Which of the following hydrate is diamagnetic ?

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  6. Which one of the following will show paramagnetism corresponding to 2 ...

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  7. CN^(-) is a strong field ligand. This is due to the fact that

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  8. [Se(H2 O)6]^(3+) ion is

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  9. The crystal field stabilization energy (CFSE) is the highest for

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  10. Which of the following complex ion is not expected to absorb visible l...

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  11. Crystal field stabilization energy for high spin d^4 octahedral comple...

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  12. A solution containing 2.675 g of CoCl(3).6NH(3) (molar mass = 267.5 g ...

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  13. Of the following complex ions, which is diamagnetic in natures?

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  14. The d-electron configurations of Cr^(2+), Mn^(2+), Fe^(2+) and Co^(2+)...

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  15. Which of the following complex compounds will exhibit highest paramagn...

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  16. Which one of the following is an outer orbital complex and exhibits pa...

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  18. Low spin complex of d^6-cation in an octahedral field will have the fo...

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  19. Among the following complexes, the one which shows zero crystal field ...

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  20. Which of the following complexes is used as an anti-cancer agent:

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