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The d-electron configurations of Cr^(2+)...

The d-electron configurations of `Cr^(2+), Mn^(2+), Fe^(2+)` and `Co^(2+)` are `d^4, d^5, d^6` and `d^7` respectively. Which one of the following will exhibit minimum paramagnetic behavious?

A

`[Co(H_2 O)_6]^(2+)`

B

`[Cr(H_2 O)_6]^(2+)`

C

`[Mn(H_2O)_6]^(2+)`

D

`[Fe(H_2 O)_6]^(2+)`

Text Solution

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The correct Answer is:
A

`[Co(H_2 O)_6]^(2+)`
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DISHA PUBLICATION-COORDINATION COMPOUNDS -Exercise
  1. Arrange the following in increasing value of magnetic moments. (i) ...

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  2. Which of the following complex is an outer orbital complex?

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  3. Which of the following order of stability of complex ion is Incorrect ...

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  4. The correct order of the stoichiometries of AgCl formed when AgNO3 in ...

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  5. Which of the following statement is correct for the complex Ca(2)[Fe(C...

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  6. The magnetic moment of complex (A) of Co was found to be 4.89BM and th...

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  7. In which of the following species the hybrid state of the central atom...

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  8. Which of the following molecule do not have the same number of unpaire...

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  9. Which of the following complex ion(s) is/are not expected to absorb vi...

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  10. The d-electron configurations of Cr^(2+), Mn^(2+), Fe^(2+) and Co^(2+)...

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  11. The oxidation number of Co in the complex ion

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  12. Match the geometry (given in columnA) with the complexes (given in col...

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  13. [Fe(en)(2)(H(2)O)(2)]^(2+) +en to " complex(X)". The correct statement...

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  14. [NiCl(2){P(C(2)H(5))(2)(C(6)H(5))}(2)] exhibits temperature dependent ...

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  15. Which of the following organometallic compound is a sigma and pi bonde...

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  16. Among the following, which is not the pi-bonded organometallic compoun...

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  17. The coordination number, EAN of the central metal atom and geometry of...

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  18. The pi - bounded organometallic compound which has ethylene as one of ...

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  19. In isolated condition C-C bond length of C(2)H(4) is x, then the bond ...

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  20. The number of sigma and pi-bonds in Fe(2)(CO)(9) is .

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