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Two moles of an ideal gas have an ...

Two moles of an ideal gas have an initial kelvin temperature `T_i` and absolute pressure `P_i` the gas undergoes a reversible isothermal compression from an initial volume `V_i` to a final volume 0.5 `V_i`
How much heat is exchanged with the environment? If heat is exchanged, is it absorbed or released?

A

`p_i V_i `(In a) , Released

B

`P_i V_i `(In 2) ,absorbed

C

`(0.5 ) P_i v_i ` released

D

`( 0.5 ) P_i V_i` absorbed

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of how much heat is exchanged with the environment during the isothermal compression of an ideal gas, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Process**: - The gas undergoes a reversible isothermal compression. This means the temperature remains constant throughout the process. 2. **Identify Given Values**: - Number of moles of gas, \( n = 2 \) moles. - Initial temperature, \( T_i \) (in Kelvin). - Initial volume, \( V_i \). - Final volume, \( V_f = 0.5 V_i \). 3. **Work Done in Isothermal Process**: - The work done \( W \) during an isothermal process can be calculated using the formula: \[ W = nRT \ln\left(\frac{V_f}{V_i}\right) \] - Here, \( V_f = 0.5 V_i \), so: \[ W = nRT \ln\left(\frac{0.5 V_i}{V_i}\right) = nRT \ln(0.5) = nRT \ln\left(\frac{1}{2}\right) = -nRT \ln(2) \] 4. **First Law of Thermodynamics**: - According to the first law of thermodynamics: \[ \Delta Q = \Delta U + W \] - For an isothermal process, the change in internal energy \( \Delta U = 0 \) (since temperature is constant). - Therefore: \[ \Delta Q = W \] 5. **Calculate Heat Exchanged**: - Substitute the expression for work into the equation for heat exchanged: \[ \Delta Q = -nRT \ln(2) \] 6. **Interpret the Result**: - The negative sign indicates that heat is released from the system to the environment during the compression process. ### Final Answer: The amount of heat exchanged with the environment is: \[ \Delta Q = -2RT_i \ln(2) \] This heat is released (since \( \Delta Q < 0 \)). ---
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