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Which of the following will not show mut...

Which of the following will not show mutarotation?

A

Maltose

B

Lactose

C

Glucose

D

Sucrose

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The correct Answer is:
To determine which of the following sugars will not show mutarotation, we need to understand the concept of mutarotation and the structural characteristics of the given sugars: maltose, lactose, glucose, and sucrose. ### Step-by-Step Solution: 1. **Understanding Mutarotation**: - Mutarotation is the change in the optical rotation of a sugar solution as it reaches equilibrium between its anomers (alpha and beta forms). This phenomenon occurs due to the interconversion of these anomers in solution. 2. **Identifying Anomers**: - Anomers are specific types of stereoisomers that differ at the anomeric carbon (the carbon that was the carbonyl carbon in the open-chain form). For a sugar to show mutarotation, it must have an anomeric carbon that can exist in both alpha and beta forms. 3. **Analyzing the Sugars**: - **Glucose**: - Glucose is a monosaccharide with a free aldehyde group. It can exist in both alpha and beta forms, thus it shows mutarotation. - **Lactose**: - Lactose is a disaccharide composed of glucose and galactose. It also has a free aldehyde group and can show mutarotation. - **Maltose**: - Maltose is another disaccharide made up of two glucose units. It has a free aldehyde group and can show mutarotation. - **Sucrose**: - Sucrose is a disaccharide composed of glucose and fructose. In sucrose, the anomeric carbon of both glucose and fructose is involved in the glycosidic bond, which means there is no free aldehyde or ketone group available for mutarotation. 4. **Conclusion**: - Since sucrose does not have a free aldehyde or ketone group, it cannot form anomers and therefore will not show mutarotation. The correct answer is **sucrose**. ### Final Answer: **Sucrose will not show mutarotation.**

To determine which of the following sugars will not show mutarotation, we need to understand the concept of mutarotation and the structural characteristics of the given sugars: maltose, lactose, glucose, and sucrose. ### Step-by-Step Solution: 1. **Understanding Mutarotation**: - Mutarotation is the change in the optical rotation of a sugar solution as it reaches equilibrium between its anomers (alpha and beta forms). This phenomenon occurs due to the interconversion of these anomers in solution. 2. **Identifying Anomers**: ...
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DISHA PUBLICATION-BIOMOLECULES -Exercise - 2 : Concept Applicator
  1. Which of the following will not show mutarotation?

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  2. Vitamin D is also known as

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  3. Which of the following pairs of compounds can be distinguished by usin...

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  4. Which of the following carbohydrates is not related to (+)-glucose?

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  5. Number of possible stereoisomers of glucose and fructose.

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  6. For the complex conversion of D-glucose into the corresponding osazone...

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  7. Which reagents can be used to distinguish glucose and fructose ? (I)...

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  8. Among the three compounds shown below, two yield the same product on r...

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  9. A distinctive and characteristic functional group of fat is

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  10. Iso-electric point of alanine is (pH =6). At which pH, maximum concent...

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  11. Find iso-electric point of given amino acid CH(3)-underset(o+)unders...

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  12. A biological catalyst is essentially

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  13. In an amino acid, the carboxyl group ionises at pK(a1) = 2.34 and ammo...

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  14. Which of the following statements is incorrect?

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  15. Among the following vitamins the one whose deficiency causes rickets (...

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  16. Which of the following statements is correct?

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  17. Which of the following is known as the universal energy currency of th...

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  18. The base present in DNA, but not in RNA is

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  19. Double stranded DNA virus with 20,000 base pairs has nucleotides

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  20. Fructose reduces Tollens' reagent due to :

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  21. Which one of the following statements is not true regarding ( +) Lacto...

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