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For 'invert sugar', the total number of ...

For 'invert sugar', the total number of correct statement(s) is(are)
(Given : specific rotations of (+) -sucrose, (+)-maltose, L-(-)-glucose and L-(+) fructose in aqueous solution are + 66°, + 140°, -52° and `+92^(@)` respectively)
(I) ‘invert sugar’ is prepared by acid catalyzed hydrolysis of maltose.
(II) ‘invert sugar’ is an equimolar mixture of D-(+)~giucose and D-(-)-fruetose.
(III) specific rotation of‘invert sugar’ is -20°.
(IV) on reaction with `Br_2` water, ‘invert sugar’ forms saccharic acid as one of the products.

Text Solution

Verified by Experts

The correct Answer is:
2

(2) Invert sugar is an equimolar mixture of D-(+) glucose and D(-) glucose.
`underset(+"sucrose")(C_(12)H_(22)O_(11)) + H_(2)O overset(H^(+)) to underset("invert sugar")(C_(6)H_(12)O_(6) + O_(2) overset(+)to C_(6)H_(12)O_(6))`
Specific rotation of invert sugar = `(-92^(@)+52^(@))/2 = -20^(@)`
D-glucose on oxidation with `Br_(2-)` water produces gluconic acid and not saccharic acid.
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Invert sugar is:

For 'invert sugar' the correct statement(s) is (are) . Give : specific rotations of (+) -sucrose , (+) - maltose , L- (-) glucose and L-(+) -fructose in aqueous solution are +66^@, +140^@,-52^@ and 92^@ , respectively.

Knowledge Check

  • An invert sugar is

    A
    isorotatory
    B
    dextrorotatory
    C
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    D
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  • Invert sugar is :

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    B
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    C
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    D
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