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The rate of a reaction quadruples when t...

The rate of a reaction quadruples when the temperature changes from 300 to 310 K. The activation energy of this reaction is `:`
( Assume Activation energy and pre-exponential factor are independent of temperature, `ln(2) = 0.693, R = 8.314J - mol^(-1) K^(-1))`

A

`107.2 kJ mol^(-1)`

B

`53.6 kJ mol^(-1)`

C

`26.8 kJ mol^(-1)`

D

`214.4 kJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

In `(K_(2))/(K_(1))=(E_(a))/(R)((1)/(T_(1))-(1)/(T_(2)))`
In `4=(E_(a))/(8.314)((310-300)/(310 xx 300))`
`2 In 2=(E_(a))/(8.314)((310-300)/(310 xx 300))`
`E_(a)=(0.693 xx 2 xx 8.314 xx 300 xx 310)/(10)=107.2 KJ // mol`
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