Home
Class 12
CHEMISTRY
(i) On the basis of the standard electro...

(i) On the basis of the standard electrode potential values stated for acid solutions, predict whether `Ti^(4+)` species may be used to oxidise Fe(II) to Fe(III)
`{:(Ti^(4+) + e^(-) to Ti^(3+), E^(@) = +0.01V), (Fe^(3+) + e^(-) to Fe^(2+), E^(@)= +0.77V):}`
(ii) Based on the data arrange `Fe^(3+), Mn^(2+) " and " Cr^(2+)` in the increasing order of stability of +2 oxidation state. (Give a brief reason)
`E_(Cr^(3+)//Cr^(2+))^(@) = -0.4V`
`E_(Mn^(3+)//Mn^(2+))^(@) = +1.5V`
`E_(Fe^(3+)//Fe^(2+))^(@) = +0.8V`

Text Solution

Verified by Experts

As the value of reduction potential increases the stability of +2 oxidation state increases . Therefore correct order of stability is
` Cr^(3+) | Cr^(2+) lt Fe^(3+) |Fe^(2+) lt Mn^(3+) | Mn^(2+)`
Promotional Banner

Topper's Solved these Questions

  • D AND F-BLOCK ELEMENTS

    MODERN PUBLICATION|Exercise NCERT FILE (INTEXT QUESTION)|10 Videos
  • D AND F-BLOCK ELEMENTS

    MODERN PUBLICATION|Exercise NCERT FILE (TEXTBOOK EXERCISE)|38 Videos
  • D AND F-BLOCK ELEMENTS

    MODERN PUBLICATION|Exercise PRACTICE PROBLEM|33 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|13 Videos
  • ELECTROCHEMISTRY

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|20 Videos

Similar Questions

Explore conceptually related problems

On the basis of the standard electroe potential values stated for acid solution, predict whether, Ti^(4+) species may be used to oxidise Fe^(II) " to " Fe^(III) . Given. Ti^(4+) +_e^(-) to Ti^(3+),E^(ɵ)=+0.01 V,Fe^(3+)+e^(-) to Fe^(2+),E^(ɵ)=+0.77 V

On the basis of the standard electrode potential velues, state whether Ti^(4+) species can be used to oxidise Fe(II) to Fe(III). Ti^(4+)+e^(-) to Ti^(3+)," "E^(@)=+0.1 V Fe^(3+)+e^(-) to Fe^(2+)," "E^(@)=+0.77 V

If E_(Fe^(2+)//Fe)^(@)=-0.440 V and E_(Fe^(3+)//Fe^(2+))^(@)=0.770 V , then E_(Fe^(3+)//Fe)^(@) is -

Show that E_(Fe^(+3)//Fe^(+2))^(@) =3E_(Fe^(+3)//Fe)^(@)-2E_(Fe^(+2)//Fe)^(@)

MODERN PUBLICATION-D AND F-BLOCK ELEMENTS-CONCEPTUAL QUESTION
  1. Silver is a transition metal but zinc is not.

    Text Solution

    |

  2. The magnetic moments of few transition metal ions are given below : ...

    Text Solution

    |

  3. (i) On the basis of the standard electrode potential values stated for...

    Text Solution

    |

  4. (a) Why do transition elements show variable oxidation states? (i) N...

    Text Solution

    |

  5. When MnO2 is fused with KOH in the presence of KNO3 as an oxidising a...

    Text Solution

    |

  6. (a) Write a metal oxide compound for manganese in each of the followin...

    Text Solution

    |

  7. How many water molecules are involved in coordination in CuSO4 .5H2O ...

    Text Solution

    |

  8. Work out the following using chemical equation. In moist air, copper...

    Text Solution

    |

  9. What is the most common form of chromium in basic solution ? What ion ...

    Text Solution

    |

  10. Explain how the colour of K2Cr2O7 solution depends on pH of the solut...

    Text Solution

    |

  11. Name the oxometal anions of the first series of the transition metals ...

    Text Solution

    |

  12. Complete the following reactions : (i) Cr(2)O(7)^(2-)+Sn^(2+)+H^(+) ...

    Text Solution

    |

  13. Sodium chloride when heated with conc. H(2)SO(4) and solid potassium d...

    Text Solution

    |

  14. Give reasons for following in one or two sentences: CrO3 is an acid ...

    Text Solution

    |

  15. Complete the following chemical equations : (i) KMnO4 overset(513K...

    Text Solution

    |

  16. Why KMnO(4) is used in cleaning surgical instruments in hospitals ?

    Text Solution

    |

  17. Identify the oxoanion of chromium which is stable in acidic medium

    Text Solution

    |

  18. In the transition series, starting from lanthanum La(Z=57), the next e...

    Text Solution

    |

  19. One among the lanthanoides, Ce(III), can be easily oxidized to Ce(IV) ...

    Text Solution

    |

  20. Why do Zr and Hf exhibit similar properties ?

    Text Solution

    |