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The 4d and 5d series of transition metal...

The 4d and 5d series of transition metals have more frequency metal-metal bonding in their compounds than do the 3d metals. Explain.

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In the same group of d-block elements, the 4d and 5d transition elements have larger size than that of 3d-element. Therefore, their valence electrons are less tightly held and can form metal-metal bond more frequently. This is the reason that melting points and enthalpies of atomisation of elements of 4d and 5d-series are higher than those of 3d series.
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MODERN PUBLICATION-D AND F-BLOCK ELEMENTS-HIGHER ORDER THINKING SKILLS
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  4. Mercurous ion is written as Hg(2)^(2+) whereas cuprous ion is written ...

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  5. In the titration of Fe^(2+) ions with KMnO4 in acidic medium, why is ...

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  6. Why hydrated copper sulphate is blue while anhydrous copper sulphate i...

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  7. Which of two : cuprous chloride or cupric chloride is coloured and why...

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  8. A mixed oxide of iron and chromium, FeO.Cr2O3 is fused with sodium car...

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  9. Calculate the magnetic moment (spin only) of manganese in K4 [Mn(NCS)...

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  10. HgCl2 and SnCl2 cannot coexist together in an aqueous solution.

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  11. In the transition series, starting from lanthanum La(Z=57), the next e...

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  12. The 4d and 5d series of transition metals have more frequency metal-me...

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  13. Between Na^(+) and Ag^(+) which is stronger Lewis acid and why?

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  14. Identify A to E. Pyrolusite on heating with KOH in the presence of air...

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