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The major product of the following react...

The major product of the following reaction is:
`CH_3underset(Br)underset(|)CHCH_2underset(Br)underset(|)CHCH_2CH_3overset(KOH,CH_3OH)underset(heat)rarr`

A

`CH_2=CHCH_2CH=CHCH_3`

B

`CH_2=CHCH=CHCH_2CH_3`

C

`CH_3CH=C=CHCH_2CH_3`

D

`CH_3CH=CH-CH=CHCH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the given reaction, we will follow these steps: ### Step 1: Identify the Reactants The reactants are: - 1-bromo-2-methylbutane (CH3-CHBr-CH2-CHBr-CH2-CH3) - KOH in methanol with heat ### Step 2: Understand the Reaction Type The presence of KOH (a strong base) and heat suggests that this reaction will undergo an elimination reaction (E2 mechanism), where bromine (Br) will be eliminated along with a hydrogen atom (H) to form a double bond. ### Step 3: Identify the Possible Elimination Sites In the structure, we have two bromine atoms that can be eliminated: 1. The bromine on the first carbon (1-bromo) 2. The bromine on the second carbon (2-bromo) ### Step 4: Determine the Elimination Pathway - If the bromine on the first carbon is eliminated, the hydrogen from the adjacent carbon (the second carbon) will be abstracted, leading to the formation of a double bond between the first and second carbons. - If the bromine on the second carbon is eliminated, the hydrogen from the adjacent carbon (the third carbon) will be abstracted, leading to the formation of a double bond between the second and third carbons. ### Step 5: Analyze the Stability of the Alkenes Formed - **Elimination of Br from the first carbon**: - Forms CH2=CH-CH2-CH2-CH3 (1-pentene) - **Elimination of Br from the second carbon**: - Forms CH3-CH=CH-CH2-CH3 (2-pentene) The stability of alkenes is influenced by the number of alkyl substituents on the double bond. The more substituted the double bond, the more stable the alkene. ### Step 6: Determine the Major Product In this case, 2-pentene (formed by the elimination of Br from the second carbon) is more stable than 1-pentene because it is more substituted (the double bond is between the second and third carbons, which has more alkyl groups attached). ### Conclusion The major product of the reaction is **2-pentene (CH3-CH=CH-CH2-CH3)**. ---

To determine the major product of the given reaction, we will follow these steps: ### Step 1: Identify the Reactants The reactants are: - 1-bromo-2-methylbutane (CH3-CHBr-CH2-CHBr-CH2-CH3) - KOH in methanol with heat ### Step 2: Understand the Reaction Type ...
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DISHA PUBLICATION-HALOALKANES AND HALOARENES -Exercise -2 : Concept Applicator
  1. The major product of the following reaction is: CH3underset(Br)und...

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  2. The decreasing order of reactivity of meta-nitrobrombenzene (I) 2,4,6-...

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  3. Although hexafluoroethane (C2F6,b.p.-79^@C) and ethane (C2H6 b.p. – 89...

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  4. Consider the following anions. When attached to sp^3-hydridiz...

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  5. Which of the following si most reactive toward S(N^(2)) reaction ?

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  6. Which Is a true statement concering the transition state of an S(N^(2)...

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  7. In the following reaction, compound (B) is

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  8. Identify correct reactivity order for SN1 reaction

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  9. then A is

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  10. CH3CH2Cloverset(NaCN)rarrXoverset(Ni//H2)rarrY Yoverset(Acetic)und...

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  11. Isobutene overset(HBr)underset("peroxide")rarrAoverset(KCN)rarrBoverse...

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  12. X in the following reaction is Br2+overset(CH3-C-H)underset(H-C-CH...

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  13. PhCOCHBr(2)overset(OH^(-))toAoverset(OH^(-))toBoverset(H^(+))toC The...

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  14. Which of the following statements is correct?

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  15. CH3-CH2-undersetunderset(Cl)|CH CH3 obtained by chlorination of n buta...

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  16. Which of the following is fast de-brominated ?

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  17. Which chloroderivative of benzene among the following would undergo hy...

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  18. The compound C7H8overset(3Cl2/Delta)rarrAoverset(Br2/Fe)rarrBoverse...

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  19. Which compound in each of the following pairs is most reactive to the ...

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  20. Chlorobenzene reacts with trichloro acetaldehyde in the presence of H2...

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  21. In the following sequence of reaction CH(3)-Br overset(KCN)rarrA ove...

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