Home
Class 12
CHEMISTRY
For the compounds CH3Cl,CH3Br,CH3I "...

For the compounds
`CH_3Cl,CH_3Br,CH_3I "and" CH_3F`
the correct order of increasing C-halogen bond length is:

A

`CH_3F lt CH_3Cl lt CH_3Br lt CH_3I`

B

`CH_3F lt CH_3Br lt CH_3Cl lt CH_3I`

C

`CH_3F lt CH_3I lt CH_3Br lt CH_3Cl`

D

`CH_3Cl lt CH_3Br lt CH_3F lt CH_3I`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of increasing C-halogen bond length for the compounds CH₃Cl, CH₃Br, CH₃I, and CH₃F, we need to consider the size of the halogen atoms and how that affects the bond length. ### Step-by-Step Solution: 1. **Identify the Halogens and Their Sizes**: - The halogens involved are Fluorine (F), Chlorine (Cl), Bromine (Br), and Iodine (I). - The atomic sizes of these halogens increase in the order: F < Cl < Br < I. - This means that Fluorine is the smallest atom, while Iodine is the largest. 2. **Understanding Bond Length**: - Bond length is the distance between the nuclei of two bonded atoms. - As the size of the halogen atom increases, the bond length between carbon and the halogen also increases. 3. **Comparing the Bond Lengths**: - For CH₃F, the bond length will be the shortest because Fluorine is the smallest halogen. - For CH₃Cl, the bond length will be longer than CH₃F, as Chlorine is larger than Fluorine. - For CH₃Br, the bond length will be longer than CH₃Cl, as Bromine is larger than Chlorine. - For CH₃I, the bond length will be the longest because Iodine is the largest halogen. 4. **Establishing the Order**: - Therefore, the order of increasing C-halogen bond length is: - CH₃F < CH₃Cl < CH₃Br < CH₃I 5. **Final Answer**: - The correct order of increasing C-halogen bond length is: **CH₃F < CH₃Cl < CH₃Br < CH₃I**.

To determine the correct order of increasing C-halogen bond length for the compounds CH₃Cl, CH₃Br, CH₃I, and CH₃F, we need to consider the size of the halogen atoms and how that affects the bond length. ### Step-by-Step Solution: 1. **Identify the Halogens and Their Sizes**: - The halogens involved are Fluorine (F), Chlorine (Cl), Bromine (Br), and Iodine (I). - The atomic sizes of these halogens increase in the order: F < Cl < Br < I. - This means that Fluorine is the smallest atom, while Iodine is the largest. ...
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    DISHA PUBLICATION|Exercise Exercise-1:Concept Builder(Topicwise)(TOPIC 1:)(General Characteristics of Haloakanes and Halorenes)|9 Videos
  • HALOALKANES AND HALOARENES

    DISHA PUBLICATION|Exercise Exercise-1:Concept Builder(Topicwise)(TOPIC 2:)(Preparation and Properties of Haloalkanes)|34 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    DISHA PUBLICATION|Exercise EXERCISE -1: CONCEPT APPLICATOR|35 Videos
  • HYDROCARBONS

    DISHA PUBLICATION|Exercise EXERCISE -2 CONCEPT APPLICATOR|29 Videos

Similar Questions

Explore conceptually related problems

For the compounds, CH_(3)Cl, CH_(3)I, CH_(3)Br and which of the following is the correct order of C-halogen bond length?

For the compounds, CH_(3)Cl, CH_(3)I, CH_(3)Br and which of the following is the correct order of C-halogen bond length?

The dipole moments of CH_(3)F, CH_(3)Cl and CH_(3)Br are in the order :

Consider the following haloalkanes, I. CH_(3)l II. CH_(3)F III. CH_(3)Cl IV. CH_(3)Br The correct sequence of increasing order of dipole moment is

In the given compounds (A) CH_(3)CH_(2)CH_(2)CH_(2)-Br (B) CH_(3)-CH_(2)-underset(Br) underset(|)CH-CH_(3) (C) CH_(3)-overset(CH_(3))overset(|)underset(Br) underset(|)C-CH_(3) The correct order of boiling point is

IUPAC name of CH_3CH_2C(Br)=CH-Cl is

In S_N 2 reactions, the correct order of reactivity for the following compounds CH_3 Cl, CH_3CH_2 Cl, (CH_3)_2 CHCl and (CH_3)_3 C Cl is :

DISHA PUBLICATION-HALOALKANES AND HALOARENES -Exercise -2 : Concept Applicator
  1. For the compounds CH3Cl,CH3Br,CH3I "and" CH3F the correct orde...

    Text Solution

    |

  2. The decreasing order of reactivity of meta-nitrobrombenzene (I) 2,4,6-...

    Text Solution

    |

  3. Although hexafluoroethane (C2F6,b.p.-79^@C) and ethane (C2H6 b.p. – 89...

    Text Solution

    |

  4. Consider the following anions. When attached to sp^3-hydridiz...

    Text Solution

    |

  5. Which of the following si most reactive toward S(N^(2)) reaction ?

    Text Solution

    |

  6. Which Is a true statement concering the transition state of an S(N^(2)...

    Text Solution

    |

  7. In the following reaction, compound (B) is

    Text Solution

    |

  8. Identify correct reactivity order for SN1 reaction

    Text Solution

    |

  9. then A is

    Text Solution

    |

  10. CH3CH2Cloverset(NaCN)rarrXoverset(Ni//H2)rarrY Yoverset(Acetic)und...

    Text Solution

    |

  11. Isobutene overset(HBr)underset("peroxide")rarrAoverset(KCN)rarrBoverse...

    Text Solution

    |

  12. X in the following reaction is Br2+overset(CH3-C-H)underset(H-C-CH...

    Text Solution

    |

  13. PhCOCHBr(2)overset(OH^(-))toAoverset(OH^(-))toBoverset(H^(+))toC The...

    Text Solution

    |

  14. Which of the following statements is correct?

    Text Solution

    |

  15. CH3-CH2-undersetunderset(Cl)|CH CH3 obtained by chlorination of n buta...

    Text Solution

    |

  16. Which of the following is fast de-brominated ?

    Text Solution

    |

  17. Which chloroderivative of benzene among the following would undergo hy...

    Text Solution

    |

  18. The compound C7H8overset(3Cl2/Delta)rarrAoverset(Br2/Fe)rarrBoverse...

    Text Solution

    |

  19. Which compound in each of the following pairs is most reactive to the ...

    Text Solution

    |

  20. Chlorobenzene reacts with trichloro acetaldehyde in the presence of H2...

    Text Solution

    |

  21. In the following sequence of reaction CH(3)-Br overset(KCN)rarrA ove...

    Text Solution

    |