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In SN2 reactions, the correct order of r...

In `S_N2` reactions, the correct order of reactivity for the following compounds:
`CH_3Cl,CH_3CH_2Cl,(CH_3)_2CHCl "and" (CH_3)_3"CC"l` is :

A

`CH_3Cl gt (CH_3)_2CHCl gt CH_3CH_2Cl gt (CH_3)_3CCl`

B

`CH_3Cl gt CH_3CH_2Cl gt (CH_3)_2CHCl gt (CH_3)_3CCl`

C

`CH_3CH_2Cl gt CH_3Cl gt (CH_3)_2CHCl gt (CH_3)_3CCl`

D

`(CH_3)_2CHCl gt CH_3CH_2Cl gt CH_3Cl gt (CH_3)_3CCl`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of reactivity for the compounds in \( S_N2 \) reactions, we need to consider the steric hindrance around the carbon atom that is bonded to the halogen (in this case, chlorine). The more sterically hindered the carbon is, the slower the reaction will be due to the nucleophile's inability to effectively attack the carbon atom. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds given are: - \( CH_3Cl \) (methyl chloride) - \( CH_3CH_2Cl \) (ethyl chloride) - \( (CH_3)_2CHCl \) (isopropyl chloride) - \( (CH_3)_3CCl \) (tert-butyl chloride) 2. **Analyze Steric Hindrance**: - **Methyl Chloride (\( CH_3Cl \))**: This compound has no alkyl groups attached to the carbon bonded to chlorine, making it the least hindered and therefore the most reactive in \( S_N2 \) reactions. - **Ethyl Chloride (\( CH_3CH_2Cl \))**: This compound has one alkyl group, which introduces some steric hindrance but is still less hindered than the next compounds. - **Isopropyl Chloride (\( (CH_3)_2CHCl \))**: This compound has two alkyl groups attached, increasing the steric hindrance and making it less reactive than methyl and ethyl chlorides. - **Tert-butyl Chloride (\( (CH_3)_3CCl \))**: This compound has three alkyl groups, resulting in significant steric hindrance, making it the least reactive in \( S_N2 \) reactions. 3. **Order of Reactivity**: Based on the analysis of steric hindrance, the order of reactivity for these compounds in \( S_N2 \) reactions is: \[ CH_3Cl > CH_3CH_2Cl > (CH_3)_2CHCl > (CH_3)_3CCl \] ### Final Answer: The correct order of reactivity for the given compounds in \( S_N2 \) reactions is: \[ CH_3Cl > CH_3CH_2Cl > (CH_3)_2CHCl > (CH_3)_3CCl \]

To determine the correct order of reactivity for the compounds in \( S_N2 \) reactions, we need to consider the steric hindrance around the carbon atom that is bonded to the halogen (in this case, chlorine). The more sterically hindered the carbon is, the slower the reaction will be due to the nucleophile's inability to effectively attack the carbon atom. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds given are: - \( CH_3Cl \) (methyl chloride) - \( CH_3CH_2Cl \) (ethyl chloride) - \( (CH_3)_2CHCl \) (isopropyl chloride) ...
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DISHA PUBLICATION-HALOALKANES AND HALOARENES -Exercise -2 : Concept Applicator
  1. In SN2 reactions, the correct order of reactivity for the following co...

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  2. The decreasing order of reactivity of meta-nitrobrombenzene (I) 2,4,6-...

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  3. Although hexafluoroethane (C2F6,b.p.-79^@C) and ethane (C2H6 b.p. – 89...

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  4. Consider the following anions. When attached to sp^3-hydridiz...

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  5. Which of the following si most reactive toward S(N^(2)) reaction ?

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  6. Which Is a true statement concering the transition state of an S(N^(2)...

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  7. In the following reaction, compound (B) is

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  8. Identify correct reactivity order for SN1 reaction

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  9. then A is

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  10. CH3CH2Cloverset(NaCN)rarrXoverset(Ni//H2)rarrY Yoverset(Acetic)und...

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  11. Isobutene overset(HBr)underset("peroxide")rarrAoverset(KCN)rarrBoverse...

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  12. X in the following reaction is Br2+overset(CH3-C-H)underset(H-C-CH...

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  13. PhCOCHBr(2)overset(OH^(-))toAoverset(OH^(-))toBoverset(H^(+))toC The...

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  14. Which of the following statements is correct?

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  15. CH3-CH2-undersetunderset(Cl)|CH CH3 obtained by chlorination of n buta...

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  16. Which of the following is fast de-brominated ?

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  17. Which chloroderivative of benzene among the following would undergo hy...

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  18. The compound C7H8overset(3Cl2/Delta)rarrAoverset(Br2/Fe)rarrBoverse...

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  19. Which compound in each of the following pairs is most reactive to the ...

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  20. Chlorobenzene reacts with trichloro acetaldehyde in the presence of H2...

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  21. In the following sequence of reaction CH(3)-Br overset(KCN)rarrA ove...

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