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(CH3)3CCloverset(NaCl)rarrAoverset(dil.H...

`(CH_3)_3CCloverset(NaCl)rarrAoverset(dil.H_2SO_4)rarrB`Compound B is

A

`(CH)_3COOOH`

B

`(CH_3)_3COH`

C

`(CH_3)_3COC(CH_3)_3`

D

All the three

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The correct Answer is:
To solve the problem, we need to analyze the reactions step by step. ### Step 1: Identify the starting compound The starting compound is `(CH₃)₃CCl`, which is tert-butyl chloride (tert-butyl group with a chlorine atom). ### Step 2: Reaction with NaCl When tert-butyl chloride reacts with NaCl, we can expect a nucleophilic substitution reaction. However, since tert-butyl chloride is a tertiary halide, it is more likely to undergo an elimination reaction rather than substitution. In the presence of NaCl, the chloride ion (Cl⁻) can leave, leading to the formation of a tert-butyl cation `(CH₃)₃C⁺`. ### Step 3: Elimination Reaction The tert-butyl cation is very stable and can undergo an elimination reaction. In the presence of a strong base, such as NaCN, it can lose a proton (H⁺) to form an alkene. The elimination of H⁺ from the tert-butyl cation results in the formation of isobutylene (2-methylpropene): \[ (CH₃)₃C⁺ \rightarrow CH₂=C(CH₃)₂ \] ### Step 4: Reaction with Dilute H₂SO₄ Next, the alkene (isobutylene) reacts with dilute sulfuric acid (H₂SO₄). In this reaction, the alkene undergoes hydration. The double bond in isobutylene will react with H⁺ from H₂SO₄, leading to the formation of a carbocation. The carbocation formed can then react with water (H₂O) to form an alcohol. The water molecule acts as a nucleophile and attacks the carbocation, resulting in the formation of tert-butyl alcohol: \[ CH₂=C(CH₃)₂ + H₂O \rightarrow (CH₃)₃COH \] ### Step 5: Final Product The final product, compound B, is tert-butyl alcohol, which can be represented as: \[ (CH₃)₃COH \] ### Conclusion Thus, the compound B formed after the reactions is tert-butyl alcohol. ---

To solve the problem, we need to analyze the reactions step by step. ### Step 1: Identify the starting compound The starting compound is `(CH₃)₃CCl`, which is tert-butyl chloride (tert-butyl group with a chlorine atom). ### Step 2: Reaction with NaCl When tert-butyl chloride reacts with NaCl, we can expect a nucleophilic substitution reaction. However, since tert-butyl chloride is a tertiary halide, it is more likely to undergo an elimination reaction rather than substitution. ...
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DISHA PUBLICATION-HALOALKANES AND HALOARENES -Exercise-1:Concept Builder(Topicwise)(TOPIC 2:)(Preparation and Properties of Haloalkanes)
  1. To prepare 3-ethylpentan-3-ol, the reactants needed are

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  2. The rate of SN2 reaction is maximum when the solvent is

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  3. Identify Z, in the following reaction. C(2)H(5)l overset("alc. KOH")...

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  4. The compound most reactive towards SN1 reaction is

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  5. Which of the following is correct ?

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  6. Which of the following order is not correct?

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  7. Which of the following is an example of SN2 reaction?

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  8. Which of the following is not possible ?

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  9. Which of the statement(s) is/are true, regarding following reaction? ...

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  10. (CH3)3CCloverset(NaCl)rarrAoverset(dil.H2SO4)rarrBCompound B is

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  12. A solution of (+)2-chloro-2-phenylethane in toluene racemises slowly i...

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  13. Primary alkyl halide C(4)H(9)Br (a) reacted with alcoholic KOH to give...

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  14. Which of the following statements is wrong?

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  15. An alkyl halide with molecular formula C6H(13)Br on dehyrohalogenation...

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  16. Finkelstein reaction for the preparation of alkyl iodide is based upon...

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  17. Dehydrohalogenation by strong base is slowest in

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  18. Which of the following will not undergo nucleophilic substitution ?

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  19. Which of the following structure is more stable?

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