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CH3CH2Cloverset(NaCN)rarrXoverset(Ni//H2...

`CH_3CH_2Cloverset(NaCN)rarrXoverset(Ni//H_2)rarrY`
`Yoverset(Acetic)underset(anhydride)rarrZ`
Z in the above reaction sequence is

A

`CH_3CH_2CH_2NHCOCH_3`

B

`CH_3CH_2CH_2NH_2`

C

`CH_3CH_2CH_2CONHCH_3`

D

`CH_3CH_2CH_2CONHCOCH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem given in the question, we will follow the sequence of reactions step by step. ### Step 1: Formation of Compound X The first reaction is: \[ \text{CH}_3\text{CH}_2\text{Cl} + \text{NaCN} \rightarrow X \] - **Explanation**: Here, we have ethyl chloride (CH3CH2Cl) reacting with sodium cyanide (NaCN). Sodium cyanide provides the cyanide ion (CN⁻), which acts as a nucleophile. The cyanide ion attacks the electrophilic carbon atom in the ethyl chloride, leading to the substitution of the chlorine atom (Cl) with the cyanide group (CN). - **Result**: The product formed is: \[ X = \text{CH}_3\text{CH}_2\text{CN} \] ### Step 2: Formation of Compound Y The next reaction is: \[ X + \text{H}_2/\text{Ni} \rightarrow Y \] - **Explanation**: In this step, the compound X (CH3CH2CN) is subjected to hydrogenation using hydrogen gas (H2) in the presence of a nickel catalyst. This reaction reduces the nitrile group (CN) to an amine (NH2). The carbon chain remains the same while the CN group is converted to CH2NH2. - **Result**: The product formed is: \[ Y = \text{CH}_3\text{CH}_2\text{CH}_2\text{NH}_2 \] ### Step 3: Formation of Compound Z The final reaction is: \[ Y + \text{Acetic Anhydride} \rightarrow Z \] - **Explanation**: In this step, the amine (Y) reacts with acetic anhydride. The acetic anhydride acts as an electrophile and reacts with the amine group (NH2) to form an amide. The nitrogen atom in the amine attacks the carbonyl carbon of the acetic anhydride, leading to the formation of a new bond and the release of acetic acid. - **Result**: The product formed is: \[ Z = \text{CH}_3\text{CH}_2\text{CH}_2\text{NHCOCH}_3 \] ### Final Answer The final compound Z is: \[ Z = \text{CH}_3\text{CH}_2\text{CH}_2\text{NHCOCH}_3 \]

To solve the problem given in the question, we will follow the sequence of reactions step by step. ### Step 1: Formation of Compound X The first reaction is: \[ \text{CH}_3\text{CH}_2\text{Cl} + \text{NaCN} \rightarrow X \] - **Explanation**: Here, we have ethyl chloride (CH3CH2Cl) reacting with sodium cyanide (NaCN). Sodium cyanide provides the cyanide ion (CN⁻), which acts as a nucleophile. The cyanide ion attacks the electrophilic carbon atom in the ethyl chloride, leading to the substitution of the chlorine atom (Cl) with the cyanide group (CN). ...
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DISHA PUBLICATION-HALOALKANES AND HALOARENES -Exercise -2 : Concept Applicator
  1. Identify correct reactivity order for SN1 reaction

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  2. then A is

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  3. CH3CH2Cloverset(NaCN)rarrXoverset(Ni//H2)rarrY Yoverset(Acetic)und...

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  4. Isobutene overset(HBr)underset("peroxide")rarrAoverset(KCN)rarrBoverse...

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  5. X in the following reaction is Br2+overset(CH3-C-H)underset(H-C-CH...

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  6. PhCOCHBr(2)overset(OH^(-))toAoverset(OH^(-))toBoverset(H^(+))toC The...

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  7. Which of the following statements is correct?

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  8. CH3-CH2-undersetunderset(Cl)|CH CH3 obtained by chlorination of n buta...

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  9. Which of the following is fast de-brominated ?

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  10. Which chloroderivative of benzene among the following would undergo hy...

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  11. The compound C7H8overset(3Cl2/Delta)rarrAoverset(Br2/Fe)rarrBoverse...

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  12. Which compound in each of the following pairs is most reactive to the ...

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  13. Chlorobenzene reacts with trichloro acetaldehyde in the presence of H2...

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  14. In the following sequence of reaction CH(3)-Br overset(KCN)rarrA ove...

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  15. What products are formed when the following compound is treated with B...

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  16. In an S(N)1reaction on chiral centres, there is

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  17. In which of the following compounds , the C - Cl bond ioniosation shal...

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  18. For the following reactions : (1) CH3CH2CH2Br+KOHrarrCH3CH=CH2+KBr...

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  19. The raction of toluene with CI(2) in presence of FeCI(3) gives X and r...

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  20. Condiser the reactions, (i) (CH(3))(2)CH-CH(2)Broverset(C(2)H(5)OH)r...

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