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How many of the following complexes are ...

How many of the following complexes are optically inactive?
(i) trans-`[Co(NH_3)_4I_2]^+`
(ii) cis-`[Co(NH_3)_2(en)_2]^(3+)`
(iii) trans-`[Co(NH_3)_2(en)_2]^(3+)`

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To determine how many of the given complexes are optically inactive, we need to analyze each complex for symmetry elements. A complex is optically inactive if it possesses a plane of symmetry, a center of symmetry, or an alternate axis of symmetry. ### Step 1: Analyze the first complex - trans-`[Co(NH₃)₄I₂]⁺` 1. **Identify the geometry**: The complex is octahedral due to the coordination number of 6 (4 NH₃ and 2 I). 2. **Determine the arrangement**: In the trans configuration, the two I ligands are opposite each other. 3. **Check for symmetry**: The presence of two identical ligands (I) opposite each other creates a plane of symmetry through the center of the complex. 4. **Conclusion**: Since it has a plane of symmetry, trans-`[Co(NH₃)₄I₂]⁺` is optically inactive. ### Step 2: Analyze the second complex - cis-`[Co(NH₃)₂(en)₂]³⁺` 1. **Identify the geometry**: The complex is also octahedral. 2. **Determine the arrangement**: In the cis configuration, the two NH₃ ligands are adjacent to each other, and the two ethylenediamine (en) ligands are also adjacent. 3. **Check for symmetry**: This arrangement does not have a plane of symmetry or a center of symmetry due to the different ligands (NH₃ and en) and their positions. 4. **Conclusion**: Since it lacks symmetry elements, cis-`[Co(NH₃)₂(en)₂]³⁺` is optically active. ### Step 3: Analyze the third complex - trans-`[Co(NH₃)₂(en)₂]³⁺` 1. **Identify the geometry**: This complex is octahedral as well. 2. **Determine the arrangement**: In the trans configuration, the two NH₃ ligands are opposite each other, and the two en ligands are also opposite each other. 3. **Check for symmetry**: Similar to the first complex, the presence of identical ligands (NH₃) opposite each other creates a plane of symmetry. 4. **Conclusion**: Since it has a plane of symmetry, trans-`[Co(NH₃)₂(en)₂]³⁺` is optically inactive. ### Final Summary - **Optically inactive complexes**: - trans-`[Co(NH₃)₄I₂]⁺` - trans-`[Co(NH₃)₂(en)₂]³⁺` - **Optically active complex**: - cis-`[Co(NH₃)₂(en)₂]³⁺` Thus, **2 out of the 3 complexes are optically inactive**.

To determine how many of the given complexes are optically inactive, we need to analyze each complex for symmetry elements. A complex is optically inactive if it possesses a plane of symmetry, a center of symmetry, or an alternate axis of symmetry. ### Step 1: Analyze the first complex - trans-`[Co(NH₃)₄I₂]⁺` 1. **Identify the geometry**: The complex is octahedral due to the coordination number of 6 (4 NH₃ and 2 I). 2. **Determine the arrangement**: In the trans configuration, the two I ligands are opposite each other. 3. **Check for symmetry**: The presence of two identical ligands (I) opposite each other creates a plane of symmetry through the center of the complex. 4. **Conclusion**: Since it has a plane of symmetry, trans-`[Co(NH₃)₄I₂]⁺` is optically inactive. ...
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