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How many alkenes can be formed when n-bu...

How many alkenes can be formed when n-butylamine is treated with nitrous acid

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To determine how many alkenes can be formed when n-butylamine is treated with nitrous acid (HNO2), we can follow these steps: ### Step 1: Understand the Reaction When n-butylamine (C4H11NH2) reacts with nitrous acid, it undergoes a process called diazotization. The amine group (-NH2) is converted into a diazonium salt, which can then decompose to form alkenes. ### Step 2: Structure of n-Butylamine The structure of n-butylamine is: ``` CH3-CH2-CH2-CH2-NH2 ``` This means n-butylamine has a straight-chain structure with four carbon atoms. ### Step 3: Formation of the Diazonium Salt When n-butylamine reacts with nitrous acid, it forms a diazonium salt: ``` CH3-CH2-CH2-CH2-N2^+ (leaving as N2 gas) ``` ### Step 4: Carbocation Formation Upon decomposition of the diazonium salt, a carbocation is formed. The stability of the carbocation will influence the formation of alkenes. The carbocation formed from n-butylamine is a primary carbocation, which can rearrange to form a more stable secondary carbocation. ### Step 5: Rearrangement of Carbocation The primary carbocation can rearrange by hydride shift to form a more stable secondary carbocation: ``` CH3-CH2-CH^+-CH3 (secondary carbocation) ``` ### Step 6: Alkene Formation From the carbocation, alkenes can be formed by the loss of a proton (H+). The possible alkenes from the secondary carbocation are: 1. **But-2-ene** (CH3-CH=CH-CH3) 2. **But-1-ene** (CH2=CH-CH2-CH3) ### Step 7: Identify Different Isomers The alkenes formed can have different configurations: - **But-2-ene** can exist as: - **Cis-but-2-ene** (both methyl groups on the same side) - **Trans-but-2-ene** (methyl groups on opposite sides) ### Conclusion Thus, the total number of different alkenes that can be formed from the reaction of n-butylamine with nitrous acid is **3**: 1. But-1-ene 2. Cis-but-2-ene 3. Trans-but-2-ene ### Final Answer **3**

To determine how many alkenes can be formed when n-butylamine is treated with nitrous acid (HNO2), we can follow these steps: ### Step 1: Understand the Reaction When n-butylamine (C4H11NH2) reacts with nitrous acid, it undergoes a process called diazotization. The amine group (-NH2) is converted into a diazonium salt, which can then decompose to form alkenes. ### Step 2: Structure of n-Butylamine The structure of n-butylamine is: ``` ...
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Knowledge Check

  • Which is formed when benzylamine react with nitrous acid ?

    A
    `C_(6)H_(5)OH`
    B
    `C_(6)H_(5)ON a`
    C
    `C_(6)H_(5)N_(2)^(+)OH^(-)`
    D
    `C_(6)H_(5)CH_(2)OH`
  • Diethyl amine when treated with nitrous acid yields

    A
    diethyl ammonium nitrite
    B
    ethyl alcohol
    C
    N-nitroso diethyl amine
    D
    triethyl ammonium nitrite
  • Benzylamine reacts with nitrous acid to form

    A
    azobenzene
    B
    benzene
    C
    benzyl alcohol
    D
    phenol