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58.5 g of NaCl and 180 g of glucose were...

58.5 g of NaCl and 180 g of glucose were separately dissolved in 1000 mL of water. Identify the correct statement regarding the elevation of boiling point (bp) of the resulting solutions.

A

NaCl solution will show higher elevation of b.pt.

B

Glucose solution will show higher elevation of b.pt.

C

Both the soltuions will show equal elevation of b.pt.

D

The b.pt. of elevation will be shown by neither of the solutions

Text Solution

Verified by Experts

The correct Answer is:
A

`Delta T_(b) = i K_(b) m`
For water `rarr 1000 mL = 1000 g`
Molality of `NaCl=(w//M.W.)/("W(solvent)")xx1000`
`=(58.5//58.5)/(1000)xx1000=1m`
Molality of glucose `=(180//180)/(1000)xx1000=1m`
i for NaCl = 2, i for glucose = 1
`Delta T_(b)` for `NaCl gt Delta T_(b)` for glucose
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