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Solubility product constant (K(sp)) of s...

Solubility product constant `(K_(sp))` of salts of types `MX, MX_2 and M_3X` at temperature 'T' are `4.0 xx 10^(-8), 3.2 xx 10^(-14) and 2.7 xx 10^(-15)`, respectively. Solubilities `("mol. Dm"^(-3)` of the salts at temperature 'T' are in the order

A

`MX_(1) gt MX_(2) gt M_(3)X`

B

`M_(3)X gt MX_(2) gt MX_(1)`

C

`MX_(2) gt M_(3)X gt MX_(1)`

D

`MX_(1) gt M_(3)X gt MX_(2)`

Text Solution

Verified by Experts

The correct Answer is:
D

`{:(MX1,MX2,M3X,),(S_(1)^(2) = 4 xx 10^(-8),4S_(2)^(3) = 3.2 xx 10^(-14),27 S_(3)^(4) = 2.7 xx 10^(-15),),(S_(1) = 2 xx 10^(-4),S_(2)^(3) = 8 xx 10^(-15),S_(3)^(4) = 10^(-16),),(,S_(2) = 2 xx 10^(-5),S_(3) = 10^(-4),),( rArr S_(1) gt S_(3) gt S_(2),rArr MX_(1) gt M_(3)X gt MX_(2),,):}`
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