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The alkaline hydrolysis of ethyl acetate...

The alkaline hydrolysis of ethyl acetate is represented by the equation
`CH_(3) COOC_(2)H_(5) + NaOH to CH_(3) COONa + C_(2)H_(5) OH`
Experimentally it is found that for this reaction
`(dx)/(dt) = k [CH_(3)COOC_(2)H_(5)][NaOH]`
Then the reaction is

A

Bimolecular and of first order

B

Bimolecular and of second order

C

Pseudo-bimolecular

D

Pseudo- unimolecular

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction for the alkaline hydrolysis of ethyl acetate, we can analyze the given rate equation and the reactants involved. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction is given as: \[ \text{CH}_3\text{COOC}_2\text{H}_5 + \text{NaOH} \rightarrow \text{CH}_3\text{COONa} + \text{C}_2\text{H}_5\text{OH} \] Here, ethyl acetate (an ester) reacts with sodium hydroxide (a base). 2. **Write the Rate Law Expression**: The rate of the reaction is given by: \[ \frac{dx}{dt} = k [\text{CH}_3\text{COOC}_2\text{H}_5][\text{NaOH}] \] This indicates that the rate of reaction depends on the concentrations of both ethyl acetate and sodium hydroxide. 3. **Determine the Order of the Reaction**: In the rate law expression, the concentration of each reactant is raised to the power of its stoichiometric coefficient. Since both reactants are present in the first power: - The order with respect to ethyl acetate \([\text{CH}_3\text{COOC}_2\text{H}_5]\) is 1. - The order with respect to sodium hydroxide \([\text{NaOH}]\) is also 1. Therefore, the overall order of the reaction is: \[ \text{Order} = 1 + 1 = 2 \] 4. **Conclusion**: The reaction is a **bimolecular reaction** and is of **second order** overall. ### Final Answer: The reaction is a **second order reaction**. ---

To determine the order of the reaction for the alkaline hydrolysis of ethyl acetate, we can analyze the given rate equation and the reactants involved. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction is given as: \[ \text{CH}_3\text{COOC}_2\text{H}_5 + \text{NaOH} \rightarrow \text{CH}_3\text{COONa} + \text{C}_2\text{H}_5\text{OH} ...
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