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Match the complexes in Column I with the...

Match the complexes in Column I with their properties liested in Column II
`{:(A,[Co(NH_(3))_(4)(H_(2)O)_(2)]Cl_(2),p,"Geometrical isomers"),(B,[Pt(NH_(3))_(2)Cl_(2)],q,"Paramagnetic"),(C,[Co(H_(2)O)_(5)Cl]Cl,r,"Diamagnetic "),(D,[Ni(H_(2)O)_(6)]Cl_(2),s,"Metal ion with " +2"oxidation state"):}`

Text Solution

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The correct Answer is:
`A rarr p,q,s; B rarr p,r,s; C rarr q,s; Drarr q,s`
(A) `[Co(NH_(3))_(4)[(H_(2)O)_(2)]Cl_(2)` , oxidation state Co is `+2` `implies ` Paramagnetic , exhibits geometrical isomerism.
(B) `Pt^(2+)` , diamagnetic , square planar, geometrical isomerism `[Pt(NH_(3))_(2)Cl_(2)]dsp^(2)` hybridisation
(c ) q,s
(d) q,s
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